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Tris(2-{[2-(4-meth-oxy-phen-yl)eth-yl]imino-meth-yl}phenolato-κ(2)N,O(1))cobalt(III).

Ourari A, Ouennoughi Y, Bouacida S - Acta Crystallogr Sect E Struct Rep Online (2012)

Bottom Line: In the title compound, [Co(C(16)H(16)NO(2))(3)], the Co(III) atom is six-coordinated in an irregular octa-hedral geometry by three N,O-chelating 2-{[2-(4-meth-oxy-phen-yl)eth-yl]imino-meth-yl}phenolate groups.One of the three meth-oxy group is disordered over two sets of sites with an occupancy ratio of 0.768 (5):0.232 (5).The crystal packing can be described by alternating zigzag layers of organic ligands and CoN(3)O(3) octa-hedra along the c axis.

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ABSTRACT
In the title compound, [Co(C(16)H(16)NO(2))(3)], the Co(III) atom is six-coordinated in an irregular octa-hedral geometry by three N,O-chelating 2-{[2-(4-meth-oxy-phen-yl)eth-yl]imino-meth-yl}phenolate groups. One of the three meth-oxy group is disordered over two sets of sites with an occupancy ratio of 0.768 (5):0.232 (5). The crystal packing can be described by alternating zigzag layers of organic ligands and CoN(3)O(3) octa-hedra along the c axis. There are no classical hydrogen bonds in the structure, but C-H⋯π inter-actions occur.

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Packing diagram of (I) viewed down b-axis showing altering layers in zigzag.
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Fap2: Packing diagram of (I) viewed down b-axis showing altering layers in zigzag.


Tris(2-{[2-(4-meth-oxy-phen-yl)eth-yl]imino-meth-yl}phenolato-κ(2)N,O(1))cobalt(III).

Ourari A, Ouennoughi Y, Bouacida S - Acta Crystallogr Sect E Struct Rep Online (2012)

Packing diagram of (I) viewed down b-axis showing altering layers in zigzag.
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC3379129&req=5

Fap2: Packing diagram of (I) viewed down b-axis showing altering layers in zigzag.
Bottom Line: In the title compound, [Co(C(16)H(16)NO(2))(3)], the Co(III) atom is six-coordinated in an irregular octa-hedral geometry by three N,O-chelating 2-{[2-(4-meth-oxy-phen-yl)eth-yl]imino-meth-yl}phenolate groups.One of the three meth-oxy group is disordered over two sets of sites with an occupancy ratio of 0.768 (5):0.232 (5).The crystal packing can be described by alternating zigzag layers of organic ligands and CoN(3)O(3) octa-hedra along the c axis.

View Article: PubMed Central - HTML - PubMed

ABSTRACT
In the title compound, [Co(C(16)H(16)NO(2))(3)], the Co(III) atom is six-coordinated in an irregular octa-hedral geometry by three N,O-chelating 2-{[2-(4-meth-oxy-phen-yl)eth-yl]imino-meth-yl}phenolate groups. One of the three meth-oxy group is disordered over two sets of sites with an occupancy ratio of 0.768 (5):0.232 (5). The crystal packing can be described by alternating zigzag layers of organic ligands and CoN(3)O(3) octa-hedra along the c axis. There are no classical hydrogen bonds in the structure, but C-H⋯π inter-actions occur.

No MeSH data available.


Related in: MedlinePlus