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Aqua-(2,6-dihy-droxy-benzoato-κO(1))bis-(1,10-phenanthroline-κ(2)N,N')manganese(II) 2,6-dihy-droxy-benzoate hemihydrate.

Li Q, He L, Jin H - Acta Crystallogr Sect E Struct Rep Online (2012)

Bottom Line: In the complex cation of the title compound, [Mn(C(7)H(5)O(4))(C(12)H(8)N(2))(2)(H(2)O)](C(7)H(5)O(4))·0.5H(2)O, the Mn(II) atom has a six-coordinate octa-hedral environment defined by one carboxyl-ate O atom belonging to a 2,6-dihy-droxy-benzoate (DHB) ligand, four N atoms from two chelating 1,10-phenanthroline mol-ecules and one water mol-ecule.The lattice water mol-ecule lies on a twofold rotation axis.Inter-molecular O-H⋯O hydrogen bonds link two cations, two anions and one water mol-ecule into a dimer. π-π inter-actions between the pyridine and benzene rings and between the benzene rings are also observed [centroid-centroid distances = 3.7774 (16), 3.7912 (16) and 3.7310 (17) Å].

View Article: PubMed Central - HTML - PubMed

Affiliation: College of Materials Science and Engineering, China Jiliang University, Hangzhou 310018, People's Republic of China.

ABSTRACT
In the complex cation of the title compound, [Mn(C(7)H(5)O(4))(C(12)H(8)N(2))(2)(H(2)O)](C(7)H(5)O(4))·0.5H(2)O, the Mn(II) atom has a six-coordinate octa-hedral environment defined by one carboxyl-ate O atom belonging to a 2,6-dihy-droxy-benzoate (DHB) ligand, four N atoms from two chelating 1,10-phenanthroline mol-ecules and one water mol-ecule. The lattice water mol-ecule lies on a twofold rotation axis. Intra-molecular O-H⋯O hydrogen bonds are present in the DHB anions and complex cations. Inter-molecular O-H⋯O hydrogen bonds link two cations, two anions and one water mol-ecule into a dimer. π-π inter-actions between the pyridine and benzene rings and between the benzene rings are also observed [centroid-centroid distances = 3.7774 (16), 3.7912 (16) and 3.7310 (17) Å].

No MeSH data available.


Related in: MedlinePlus

The molecular structure of the title compound. Displacement ellipsoids are drawn at the 30% probability level.
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Fap1: The molecular structure of the title compound. Displacement ellipsoids are drawn at the 30% probability level.


Aqua-(2,6-dihy-droxy-benzoato-κO(1))bis-(1,10-phenanthroline-κ(2)N,N')manganese(II) 2,6-dihy-droxy-benzoate hemihydrate.

Li Q, He L, Jin H - Acta Crystallogr Sect E Struct Rep Online (2012)

The molecular structure of the title compound. Displacement ellipsoids are drawn at the 30% probability level.
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC3379126&req=5

Fap1: The molecular structure of the title compound. Displacement ellipsoids are drawn at the 30% probability level.
Bottom Line: In the complex cation of the title compound, [Mn(C(7)H(5)O(4))(C(12)H(8)N(2))(2)(H(2)O)](C(7)H(5)O(4))·0.5H(2)O, the Mn(II) atom has a six-coordinate octa-hedral environment defined by one carboxyl-ate O atom belonging to a 2,6-dihy-droxy-benzoate (DHB) ligand, four N atoms from two chelating 1,10-phenanthroline mol-ecules and one water mol-ecule.The lattice water mol-ecule lies on a twofold rotation axis.Inter-molecular O-H⋯O hydrogen bonds link two cations, two anions and one water mol-ecule into a dimer. π-π inter-actions between the pyridine and benzene rings and between the benzene rings are also observed [centroid-centroid distances = 3.7774 (16), 3.7912 (16) and 3.7310 (17) Å].

View Article: PubMed Central - HTML - PubMed

Affiliation: College of Materials Science and Engineering, China Jiliang University, Hangzhou 310018, People's Republic of China.

ABSTRACT
In the complex cation of the title compound, [Mn(C(7)H(5)O(4))(C(12)H(8)N(2))(2)(H(2)O)](C(7)H(5)O(4))·0.5H(2)O, the Mn(II) atom has a six-coordinate octa-hedral environment defined by one carboxyl-ate O atom belonging to a 2,6-dihy-droxy-benzoate (DHB) ligand, four N atoms from two chelating 1,10-phenanthroline mol-ecules and one water mol-ecule. The lattice water mol-ecule lies on a twofold rotation axis. Intra-molecular O-H⋯O hydrogen bonds are present in the DHB anions and complex cations. Inter-molecular O-H⋯O hydrogen bonds link two cations, two anions and one water mol-ecule into a dimer. π-π inter-actions between the pyridine and benzene rings and between the benzene rings are also observed [centroid-centroid distances = 3.7774 (16), 3.7912 (16) and 3.7310 (17) Å].

No MeSH data available.


Related in: MedlinePlus