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Di-μ-glutarato-κ(4)O(1):O(5)-bis-{aqua-[5,6-diphenyl-3-(pyridin-2-yl)-1,2,4-triazine-κ(2)N(2),N(3)]copper(II)}.

Xu W, Feng LJ - Acta Crystallogr Sect E Struct Rep Online (2012)

Bottom Line: In the centrosymmetric dinuclear title complex, [Cu(2)(C(5)H(6)O(4))(2)(C(20)H(14)N(4))(2)(H(2)O)(2)], the Cu atom displays a distorted square-pyramidal coordination environment with the basal plane occupied by two 5,6-diphenyl-3-(pyridin-2-yl)-1,2,4-triazine N atoms and two O atoms from different glutarate dianions, while a water mol-ecule is located at the apical position.Of the two water H atoms, one is engaged in an intra-molecular O-H⋯O hydrogen bond, whereas the second is engaged in an inter-molecular O-H⋯O hydrogen bond.The intermolecular hydrogen bonds lead to the formation of a chain along [010].

View Article: PubMed Central - HTML - PubMed

Affiliation: Center of Applied Solid State Chemistry Research, Ningbo University, Ningbo 315211, People's Republic of China.

ABSTRACT
In the centrosymmetric dinuclear title complex, [Cu(2)(C(5)H(6)O(4))(2)(C(20)H(14)N(4))(2)(H(2)O)(2)], the Cu atom displays a distorted square-pyramidal coordination environment with the basal plane occupied by two 5,6-diphenyl-3-(pyridin-2-yl)-1,2,4-triazine N atoms and two O atoms from different glutarate dianions, while a water mol-ecule is located at the apical position. Of the two water H atoms, one is engaged in an intra-molecular O-H⋯O hydrogen bond, whereas the second is engaged in an inter-molecular O-H⋯O hydrogen bond. The intermolecular hydrogen bonds lead to the formation of a chain along [010].

No MeSH data available.


ORTEP view of the title compound (40% thermal ellipsoids) showing the atom-labeling scheme. [Symmetry Code: (i) 1-x, 1-y, -z)]
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Fap1: ORTEP view of the title compound (40% thermal ellipsoids) showing the atom-labeling scheme. [Symmetry Code: (i) 1-x, 1-y, -z)]


Di-μ-glutarato-κ(4)O(1):O(5)-bis-{aqua-[5,6-diphenyl-3-(pyridin-2-yl)-1,2,4-triazine-κ(2)N(2),N(3)]copper(II)}.

Xu W, Feng LJ - Acta Crystallogr Sect E Struct Rep Online (2012)

ORTEP view of the title compound (40% thermal ellipsoids) showing the atom-labeling scheme. [Symmetry Code: (i) 1-x, 1-y, -z)]
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC3379125&req=5

Fap1: ORTEP view of the title compound (40% thermal ellipsoids) showing the atom-labeling scheme. [Symmetry Code: (i) 1-x, 1-y, -z)]
Bottom Line: In the centrosymmetric dinuclear title complex, [Cu(2)(C(5)H(6)O(4))(2)(C(20)H(14)N(4))(2)(H(2)O)(2)], the Cu atom displays a distorted square-pyramidal coordination environment with the basal plane occupied by two 5,6-diphenyl-3-(pyridin-2-yl)-1,2,4-triazine N atoms and two O atoms from different glutarate dianions, while a water mol-ecule is located at the apical position.Of the two water H atoms, one is engaged in an intra-molecular O-H⋯O hydrogen bond, whereas the second is engaged in an inter-molecular O-H⋯O hydrogen bond.The intermolecular hydrogen bonds lead to the formation of a chain along [010].

View Article: PubMed Central - HTML - PubMed

Affiliation: Center of Applied Solid State Chemistry Research, Ningbo University, Ningbo 315211, People's Republic of China.

ABSTRACT
In the centrosymmetric dinuclear title complex, [Cu(2)(C(5)H(6)O(4))(2)(C(20)H(14)N(4))(2)(H(2)O)(2)], the Cu atom displays a distorted square-pyramidal coordination environment with the basal plane occupied by two 5,6-diphenyl-3-(pyridin-2-yl)-1,2,4-triazine N atoms and two O atoms from different glutarate dianions, while a water mol-ecule is located at the apical position. Of the two water H atoms, one is engaged in an intra-molecular O-H⋯O hydrogen bond, whereas the second is engaged in an inter-molecular O-H⋯O hydrogen bond. The intermolecular hydrogen bonds lead to the formation of a chain along [010].

No MeSH data available.