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Tetra-μ(3)-iodido-tetra-kis-{[ethyl 2-(1H-benzimidazol-1-yl)acetate-κN(3)]copper(I)}.

Yang L, Zhang Z - Acta Crystallogr Sect E Struct Rep Online (2012)

Bottom Line: The complex mol-ecule of the tetra-nuclear cubane-type title compound, [Cu(4)I(4)(C(11)H(12)N(2)O(2))(4)], has crystallographically imposed fourfold inversion symmetry.The Cu(I) ions are coordinated in a distorted tetra-hedral geometry by an N atom of a benzimidazole ring system and three μ(3)-iodide ions, forming a Cu(4)I(4) core.In the crystal, complex mol-ecules are connected into a three-dimensional network by C-H⋯O hydrogen bonds involving H and O atoms of adjacent eth-oxy-carbonyl groups.

View Article: PubMed Central - HTML - PubMed

Affiliation: Department of General Medicine, Lanzhou University Second Hospital, Lanzhou 730030, People's Republic of China.

ABSTRACT
The complex mol-ecule of the tetra-nuclear cubane-type title compound, [Cu(4)I(4)(C(11)H(12)N(2)O(2))(4)], has crystallographically imposed fourfold inversion symmetry. The Cu(I) ions are coordinated in a distorted tetra-hedral geometry by an N atom of a benzimidazole ring system and three μ(3)-iodide ions, forming a Cu(4)I(4) core. In the crystal, complex mol-ecules are connected into a three-dimensional network by C-H⋯O hydrogen bonds involving H and O atoms of adjacent eth-oxy-carbonyl groups.

No MeSH data available.


The structure of the title complex with displacement ellipsoids drawn at the 30% probability level. Atoms labelled with suffix A, B and C are generated by the symmetry operator (2-x, 1.5-y, z), (0.25+y, 1.75-x, 0.75-z) and (1.75-y, -0.25+x, 0.75-z) respectively.
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Fap1: The structure of the title complex with displacement ellipsoids drawn at the 30% probability level. Atoms labelled with suffix A, B and C are generated by the symmetry operator (2-x, 1.5-y, z), (0.25+y, 1.75-x, 0.75-z) and (1.75-y, -0.25+x, 0.75-z) respectively.


Tetra-μ(3)-iodido-tetra-kis-{[ethyl 2-(1H-benzimidazol-1-yl)acetate-κN(3)]copper(I)}.

Yang L, Zhang Z - Acta Crystallogr Sect E Struct Rep Online (2012)

The structure of the title complex with displacement ellipsoids drawn at the 30% probability level. Atoms labelled with suffix A, B and C are generated by the symmetry operator (2-x, 1.5-y, z), (0.25+y, 1.75-x, 0.75-z) and (1.75-y, -0.25+x, 0.75-z) respectively.
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC3379124&req=5

Fap1: The structure of the title complex with displacement ellipsoids drawn at the 30% probability level. Atoms labelled with suffix A, B and C are generated by the symmetry operator (2-x, 1.5-y, z), (0.25+y, 1.75-x, 0.75-z) and (1.75-y, -0.25+x, 0.75-z) respectively.
Bottom Line: The complex mol-ecule of the tetra-nuclear cubane-type title compound, [Cu(4)I(4)(C(11)H(12)N(2)O(2))(4)], has crystallographically imposed fourfold inversion symmetry.The Cu(I) ions are coordinated in a distorted tetra-hedral geometry by an N atom of a benzimidazole ring system and three μ(3)-iodide ions, forming a Cu(4)I(4) core.In the crystal, complex mol-ecules are connected into a three-dimensional network by C-H⋯O hydrogen bonds involving H and O atoms of adjacent eth-oxy-carbonyl groups.

View Article: PubMed Central - HTML - PubMed

Affiliation: Department of General Medicine, Lanzhou University Second Hospital, Lanzhou 730030, People's Republic of China.

ABSTRACT
The complex mol-ecule of the tetra-nuclear cubane-type title compound, [Cu(4)I(4)(C(11)H(12)N(2)O(2))(4)], has crystallographically imposed fourfold inversion symmetry. The Cu(I) ions are coordinated in a distorted tetra-hedral geometry by an N atom of a benzimidazole ring system and three μ(3)-iodide ions, forming a Cu(4)I(4) core. In the crystal, complex mol-ecules are connected into a three-dimensional network by C-H⋯O hydrogen bonds involving H and O atoms of adjacent eth-oxy-carbonyl groups.

No MeSH data available.