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Chlorido{μ-2,6-bis-[(2-amino-eth-yl)imino-meth-yl]-4-chloro-phenolato}-μ-oxido-dicopper(II) trihydrate.

Zhou JJ, Xiao W, Mao JW, Zhou H - Acta Crystallogr Sect E Struct Rep Online (2012)

Bottom Line: In the title dinuclear complex, [Cu(2)(C(14)H(20)ClN(4)O)ClO]·3H(2)O, one Cu(II) cation assumes a distorted square-planar coordination geometry and the other a distorted square-pyramidal coordination geometry.Both Cu(II) cations are N,N',O-chelated by one arm of the 2,6-bis-[(2-amino-eth-yl)imino-meth-yl]-4-chloro-phenolate anion, and one oxide anion bridges the two Cu(II) cations, forming a dinuclear complex.One of the Cu(II) cations is further coordinated by an Cl(-) anion in the apical direction.

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ABSTRACT
In the title dinuclear complex, [Cu(2)(C(14)H(20)ClN(4)O)ClO]·3H(2)O, one Cu(II) cation assumes a distorted square-planar coordination geometry and the other a distorted square-pyramidal coordination geometry. Both Cu(II) cations are N,N',O-chelated by one arm of the 2,6-bis-[(2-amino-eth-yl)imino-meth-yl]-4-chloro-phenolate anion, and one oxide anion bridges the two Cu(II) cations, forming a dinuclear complex. One of the Cu(II) cations is further coordinated by an Cl(-) anion in the apical direction. In the crystal, lattice water mol-ecules are linked with the complex mol-ecule via O-H⋯Cl hydrogen bonds while O-H⋯O hydrogen bonding occurs between lattice water mol-ecules , forming three-dimensional network structure.

No MeSH data available.


A view of (I), showing the labeling of the non-H atoms and 30% probability ellipsoids. H atoms have been omitted for clarity.
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Fap1: A view of (I), showing the labeling of the non-H atoms and 30% probability ellipsoids. H atoms have been omitted for clarity.


Chlorido{μ-2,6-bis-[(2-amino-eth-yl)imino-meth-yl]-4-chloro-phenolato}-μ-oxido-dicopper(II) trihydrate.

Zhou JJ, Xiao W, Mao JW, Zhou H - Acta Crystallogr Sect E Struct Rep Online (2012)

A view of (I), showing the labeling of the non-H atoms and 30% probability ellipsoids. H atoms have been omitted for clarity.
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC3379123&req=5

Fap1: A view of (I), showing the labeling of the non-H atoms and 30% probability ellipsoids. H atoms have been omitted for clarity.
Bottom Line: In the title dinuclear complex, [Cu(2)(C(14)H(20)ClN(4)O)ClO]·3H(2)O, one Cu(II) cation assumes a distorted square-planar coordination geometry and the other a distorted square-pyramidal coordination geometry.Both Cu(II) cations are N,N',O-chelated by one arm of the 2,6-bis-[(2-amino-eth-yl)imino-meth-yl]-4-chloro-phenolate anion, and one oxide anion bridges the two Cu(II) cations, forming a dinuclear complex.One of the Cu(II) cations is further coordinated by an Cl(-) anion in the apical direction.

View Article: PubMed Central - HTML - PubMed

ABSTRACT
In the title dinuclear complex, [Cu(2)(C(14)H(20)ClN(4)O)ClO]·3H(2)O, one Cu(II) cation assumes a distorted square-planar coordination geometry and the other a distorted square-pyramidal coordination geometry. Both Cu(II) cations are N,N',O-chelated by one arm of the 2,6-bis-[(2-amino-eth-yl)imino-meth-yl]-4-chloro-phenolate anion, and one oxide anion bridges the two Cu(II) cations, forming a dinuclear complex. One of the Cu(II) cations is further coordinated by an Cl(-) anion in the apical direction. In the crystal, lattice water mol-ecules are linked with the complex mol-ecule via O-H⋯Cl hydrogen bonds while O-H⋯O hydrogen bonding occurs between lattice water mol-ecules , forming three-dimensional network structure.

No MeSH data available.