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Tetra-kis(pyridazine-κN)bis-(thio-cyanato-κN)nickel(II) pyridazine disolvate.

Wöhlert S, Wriedt M, Jess I, Näther C - Acta Crystallogr Sect E Struct Rep Online (2012)

Bottom Line: The reaction of nickel(II) thio-cyanate with an excess of pyridazine leads to single crystals of the title compound, [Ni(NCS)(2)(C(4)H(4)N(2))(4)]·2C(4)H(4)N(2).The Ni(II) cations are coordinated by two terminal N-bonded thio-cyanate anions (trans) and four pyridazine ligands in a slightly distorted octa-hedral geometry.The discrete complexes are arranged into layers parallel to the ab plane which are separated by additional non-coordinated pyridazine ligands.

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ABSTRACT
The reaction of nickel(II) thio-cyanate with an excess of pyridazine leads to single crystals of the title compound, [Ni(NCS)(2)(C(4)H(4)N(2))(4)]·2C(4)H(4)N(2). The Ni(II) cations are coordinated by two terminal N-bonded thio-cyanate anions (trans) and four pyridazine ligands in a slightly distorted octa-hedral geometry. The discrete complexes are arranged into layers parallel to the ab plane which are separated by additional non-coordinated pyridazine ligands.

No MeSH data available.


: Crystal structure of the title compound with view along the crystallographic b-axis.
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Fap2: : Crystal structure of the title compound with view along the crystallographic b-axis.


Tetra-kis(pyridazine-κN)bis-(thio-cyanato-κN)nickel(II) pyridazine disolvate.

Wöhlert S, Wriedt M, Jess I, Näther C - Acta Crystallogr Sect E Struct Rep Online (2012)

: Crystal structure of the title compound with view along the crystallographic b-axis.
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC3379122&req=5

Fap2: : Crystal structure of the title compound with view along the crystallographic b-axis.
Bottom Line: The reaction of nickel(II) thio-cyanate with an excess of pyridazine leads to single crystals of the title compound, [Ni(NCS)(2)(C(4)H(4)N(2))(4)]·2C(4)H(4)N(2).The Ni(II) cations are coordinated by two terminal N-bonded thio-cyanate anions (trans) and four pyridazine ligands in a slightly distorted octa-hedral geometry.The discrete complexes are arranged into layers parallel to the ab plane which are separated by additional non-coordinated pyridazine ligands.

View Article: PubMed Central - HTML - PubMed

ABSTRACT
The reaction of nickel(II) thio-cyanate with an excess of pyridazine leads to single crystals of the title compound, [Ni(NCS)(2)(C(4)H(4)N(2))(4)]·2C(4)H(4)N(2). The Ni(II) cations are coordinated by two terminal N-bonded thio-cyanate anions (trans) and four pyridazine ligands in a slightly distorted octa-hedral geometry. The discrete complexes are arranged into layers parallel to the ab plane which are separated by additional non-coordinated pyridazine ligands.

No MeSH data available.