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[4-(Dimethyl-amino)-pyridine-κN(1)]tri-methyl(thio-cyanato-κN)tin(IV).

Najafi E, Amini MM, Ng SW - Acta Crystallogr Sect E Struct Rep Online (2012)

Bottom Line: In the title monomeric trimethyl-tin(IV) isothio-cyanate-4,4-dimethyl-pyridine adduct, [Sn(CH(3))(3)(NCS)(C(7)H(10)N(2))], the Sn(IV) atom shows a trans-C(3)SnN(2) trigonal bipyramidal coordination.The Sn(IV) atom lies out of the equatorial plane by 0.033 (4) Å in the direction of the donor N atom of the N-heterocycle.The crystal studied was a non-merohedral twin with a minor component of 48.8 (2)%.

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ABSTRACT
In the title monomeric trimethyl-tin(IV) isothio-cyanate-4,4-dimethyl-pyridine adduct, [Sn(CH(3))(3)(NCS)(C(7)H(10)N(2))], the Sn(IV) atom shows a trans-C(3)SnN(2) trigonal bipyramidal coordination. The Sn(IV) atom lies out of the equatorial plane by 0.033 (4) Å in the direction of the donor N atom of the N-heterocycle. The crystal studied was a non-merohedral twin with a minor component of 48.8 (2)%.

No MeSH data available.


Related in: MedlinePlus

Thermal ellipsoid plot (Barbour, 2001) of (CH3)3Sn(NCS)(C7H10N2) at the 70% probability level; hydrogen atoms are drawn as spheres of arbitrary radius.
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Fap1: Thermal ellipsoid plot (Barbour, 2001) of (CH3)3Sn(NCS)(C7H10N2) at the 70% probability level; hydrogen atoms are drawn as spheres of arbitrary radius.


[4-(Dimethyl-amino)-pyridine-κN(1)]tri-methyl(thio-cyanato-κN)tin(IV).

Najafi E, Amini MM, Ng SW - Acta Crystallogr Sect E Struct Rep Online (2012)

Thermal ellipsoid plot (Barbour, 2001) of (CH3)3Sn(NCS)(C7H10N2) at the 70% probability level; hydrogen atoms are drawn as spheres of arbitrary radius.
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC3379119&req=5

Fap1: Thermal ellipsoid plot (Barbour, 2001) of (CH3)3Sn(NCS)(C7H10N2) at the 70% probability level; hydrogen atoms are drawn as spheres of arbitrary radius.
Bottom Line: In the title monomeric trimethyl-tin(IV) isothio-cyanate-4,4-dimethyl-pyridine adduct, [Sn(CH(3))(3)(NCS)(C(7)H(10)N(2))], the Sn(IV) atom shows a trans-C(3)SnN(2) trigonal bipyramidal coordination.The Sn(IV) atom lies out of the equatorial plane by 0.033 (4) Å in the direction of the donor N atom of the N-heterocycle.The crystal studied was a non-merohedral twin with a minor component of 48.8 (2)%.

View Article: PubMed Central - HTML - PubMed

ABSTRACT
In the title monomeric trimethyl-tin(IV) isothio-cyanate-4,4-dimethyl-pyridine adduct, [Sn(CH(3))(3)(NCS)(C(7)H(10)N(2))], the Sn(IV) atom shows a trans-C(3)SnN(2) trigonal bipyramidal coordination. The Sn(IV) atom lies out of the equatorial plane by 0.033 (4) Å in the direction of the donor N atom of the N-heterocycle. The crystal studied was a non-merohedral twin with a minor component of 48.8 (2)%.

No MeSH data available.


Related in: MedlinePlus