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Bis(2,S-dimethyl-dithio-carbazate-κ(2)N(3),S)(nitrato-κO)copper(II) nitrate.

Hazari SK, Dey BK, Ganguly B, Ng SW, Tiekink ER - Acta Crystallogr Sect E Struct Rep Online (2012)

Bottom Line: Polyhedron, 30, 542-548].The Cu(II) atom in each independent cation is found within a distorted square-pyramidal N(2)S(2)O coordination geometry defined by two N,S-bidentate ligands and an O atom derived from a monodentate nitrate.The primary difference between the cations is found in the relative orientations of the coordinated nitrate groups, which are directed to opposite sides of the mol-ecule.

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ABSTRACT
The title complex, [Cu(NO(3))(C(3)H(8)N(2)S(2))(2)]NO(3), represents a low-symmetry polymorph (P-1, Z = 4) of a previously reported form [P-1, Z = 2; Ali et al. (2011 ▶). Polyhedron, 30, 542-548]. The Cu(II) atom in each independent cation is found within a distorted square-pyramidal N(2)S(2)O coordination geometry defined by two N,S-bidentate ligands and an O atom derived from a monodentate nitrate. The primary difference between the cations is found in the relative orientations of the coordinated nitrate groups, which are directed to opposite sides of the mol-ecule. Supra-molecular layers along [110] and sustained by N-H⋯O inter-actions feature in the crystal packing. These are connected along the c axis by C-H⋯O inter-actions.

No MeSH data available.


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A view of the unit-cell contents in projection down the a axis in (I). The N—H···O and C—H···O interactions are shown as blue and orange dashed lines, respectively.
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Fap4: A view of the unit-cell contents in projection down the a axis in (I). The N—H···O and C—H···O interactions are shown as blue and orange dashed lines, respectively.


Bis(2,S-dimethyl-dithio-carbazate-κ(2)N(3),S)(nitrato-κO)copper(II) nitrate.

Hazari SK, Dey BK, Ganguly B, Ng SW, Tiekink ER - Acta Crystallogr Sect E Struct Rep Online (2012)

A view of the unit-cell contents in projection down the a axis in (I). The N—H···O and C—H···O interactions are shown as blue and orange dashed lines, respectively.
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC3379110&req=5

Fap4: A view of the unit-cell contents in projection down the a axis in (I). The N—H···O and C—H···O interactions are shown as blue and orange dashed lines, respectively.
Bottom Line: Polyhedron, 30, 542-548].The Cu(II) atom in each independent cation is found within a distorted square-pyramidal N(2)S(2)O coordination geometry defined by two N,S-bidentate ligands and an O atom derived from a monodentate nitrate.The primary difference between the cations is found in the relative orientations of the coordinated nitrate groups, which are directed to opposite sides of the mol-ecule.

View Article: PubMed Central - HTML - PubMed

ABSTRACT
The title complex, [Cu(NO(3))(C(3)H(8)N(2)S(2))(2)]NO(3), represents a low-symmetry polymorph (P-1, Z = 4) of a previously reported form [P-1, Z = 2; Ali et al. (2011 ▶). Polyhedron, 30, 542-548]. The Cu(II) atom in each independent cation is found within a distorted square-pyramidal N(2)S(2)O coordination geometry defined by two N,S-bidentate ligands and an O atom derived from a monodentate nitrate. The primary difference between the cations is found in the relative orientations of the coordinated nitrate groups, which are directed to opposite sides of the mol-ecule. Supra-molecular layers along [110] and sustained by N-H⋯O inter-actions feature in the crystal packing. These are connected along the c axis by C-H⋯O inter-actions.

No MeSH data available.


Related in: MedlinePlus