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Bis(4'-chloro-2,2':6',2''-terpyridine-κ(3)N,N',N'')ruthenium(II) dichloride dihydrate.

Wang Y, Jiao R, Qiu XL, Wang J, Huang W - Acta Crystallogr Sect E Struct Rep Online (2012)

Bottom Line: In the cation of the title compound, [Ru(C(15)H(10)ClN(3))(2)]Cl(2)·2H(2)O, the metal atom exhibits a distorted octa-hedral coordination geometry provided by the N atoms of two tridentate terpyridine ligands.The ligands are approximately planar [maximum deviation = 0.156 (5) Å] and form a dihedral angle of 87.0 (3)°.In the crystal, the cations, anions and water mol-ecules are linked into a three-dimensional network by C-H⋯Cl, C-H⋯O and O-H⋯Cl hydrogen bonds.

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ABSTRACT
In the cation of the title compound, [Ru(C(15)H(10)ClN(3))(2)]Cl(2)·2H(2)O, the metal atom exhibits a distorted octa-hedral coordination geometry provided by the N atoms of two tridentate terpyridine ligands. The ligands are approximately planar [maximum deviation = 0.156 (5) Å] and form a dihedral angle of 87.0 (3)°. In the crystal, the cations, anions and water mol-ecules are linked into a three-dimensional network by C-H⋯Cl, C-H⋯O and O-H⋯Cl hydrogen bonds.

No MeSH data available.


The asymmetric unit of the title compound with displacement ellipsoids drawn at the 30% probability level.
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Fap1: The asymmetric unit of the title compound with displacement ellipsoids drawn at the 30% probability level.


Bis(4'-chloro-2,2':6',2''-terpyridine-κ(3)N,N',N'')ruthenium(II) dichloride dihydrate.

Wang Y, Jiao R, Qiu XL, Wang J, Huang W - Acta Crystallogr Sect E Struct Rep Online (2012)

The asymmetric unit of the title compound with displacement ellipsoids drawn at the 30% probability level.
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC3379109&req=5

Fap1: The asymmetric unit of the title compound with displacement ellipsoids drawn at the 30% probability level.
Bottom Line: In the cation of the title compound, [Ru(C(15)H(10)ClN(3))(2)]Cl(2)·2H(2)O, the metal atom exhibits a distorted octa-hedral coordination geometry provided by the N atoms of two tridentate terpyridine ligands.The ligands are approximately planar [maximum deviation = 0.156 (5) Å] and form a dihedral angle of 87.0 (3)°.In the crystal, the cations, anions and water mol-ecules are linked into a three-dimensional network by C-H⋯Cl, C-H⋯O and O-H⋯Cl hydrogen bonds.

View Article: PubMed Central - HTML - PubMed

ABSTRACT
In the cation of the title compound, [Ru(C(15)H(10)ClN(3))(2)]Cl(2)·2H(2)O, the metal atom exhibits a distorted octa-hedral coordination geometry provided by the N atoms of two tridentate terpyridine ligands. The ligands are approximately planar [maximum deviation = 0.156 (5) Å] and form a dihedral angle of 87.0 (3)°. In the crystal, the cations, anions and water mol-ecules are linked into a three-dimensional network by C-H⋯Cl, C-H⋯O and O-H⋯Cl hydrogen bonds.

No MeSH data available.