Limits...
Bis(2-amino-5-methyl-1,3,4-thia-diazole-κN(3))dichloridocobalt(II).

Song Y, Ji YF, Kang MY, Liu ZL - Acta Crystallogr Sect E Struct Rep Online (2012)

Bottom Line: In the monomeric title complex, [CoCl(2)(C(3)H(5)N(3)S)(2)], the Co(II) atom is tetra-coordinated by two chloride anions and two N atoms from two monodentate 2-amino-5-methyl-1,3,4-thia-diazole ligands, giving a slightly distorted tetra-hedral stereochemistry [bond angle range about Co = 105.16 (12)-112.50 (10)°].In the complex, the dihedral angle between the 1,3,4-thia-diazole planes in the two ligands is 72.8 (1)°.There are two intra-molecular N-H⋯Cl inter-actions in the complex unit, while in the crystal, inter-molecular N-H⋯N and N-H⋯Cl hydrogen bonds link these units into a two-dimensional layered structure parallel to (011).

View Article: PubMed Central - HTML - PubMed

Affiliation: College of Chemistry and Chemical Engineering, Inner Mongolia University, Hohhot, People's Republic of China.

ABSTRACT
In the monomeric title complex, [CoCl(2)(C(3)H(5)N(3)S)(2)], the Co(II) atom is tetra-coordinated by two chloride anions and two N atoms from two monodentate 2-amino-5-methyl-1,3,4-thia-diazole ligands, giving a slightly distorted tetra-hedral stereochemistry [bond angle range about Co = 105.16 (12)-112.50 (10)°]. In the complex, the dihedral angle between the 1,3,4-thia-diazole planes in the two ligands is 72.8 (1)°. There are two intra-molecular N-H⋯Cl inter-actions in the complex unit, while in the crystal, inter-molecular N-H⋯N and N-H⋯Cl hydrogen bonds link these units into a two-dimensional layered structure parallel to (011).

No MeSH data available.


The structure and atom-numbering scheme for the title complex, with displacement ellipsoids drawn at the 30% probability level for non-H atoms. N—H···Cl interactions are shown as dashed lines.
© Copyright Policy - open-access
Related In: Results  -  Collection

License
getmorefigures.php?uid=PMC3379105&req=5

Fap1: The structure and atom-numbering scheme for the title complex, with displacement ellipsoids drawn at the 30% probability level for non-H atoms. N—H···Cl interactions are shown as dashed lines.


Bis(2-amino-5-methyl-1,3,4-thia-diazole-κN(3))dichloridocobalt(II).

Song Y, Ji YF, Kang MY, Liu ZL - Acta Crystallogr Sect E Struct Rep Online (2012)

The structure and atom-numbering scheme for the title complex, with displacement ellipsoids drawn at the 30% probability level for non-H atoms. N—H···Cl interactions are shown as dashed lines.
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC3379105&req=5

Fap1: The structure and atom-numbering scheme for the title complex, with displacement ellipsoids drawn at the 30% probability level for non-H atoms. N—H···Cl interactions are shown as dashed lines.
Bottom Line: In the monomeric title complex, [CoCl(2)(C(3)H(5)N(3)S)(2)], the Co(II) atom is tetra-coordinated by two chloride anions and two N atoms from two monodentate 2-amino-5-methyl-1,3,4-thia-diazole ligands, giving a slightly distorted tetra-hedral stereochemistry [bond angle range about Co = 105.16 (12)-112.50 (10)°].In the complex, the dihedral angle between the 1,3,4-thia-diazole planes in the two ligands is 72.8 (1)°.There are two intra-molecular N-H⋯Cl inter-actions in the complex unit, while in the crystal, inter-molecular N-H⋯N and N-H⋯Cl hydrogen bonds link these units into a two-dimensional layered structure parallel to (011).

View Article: PubMed Central - HTML - PubMed

Affiliation: College of Chemistry and Chemical Engineering, Inner Mongolia University, Hohhot, People's Republic of China.

ABSTRACT
In the monomeric title complex, [CoCl(2)(C(3)H(5)N(3)S)(2)], the Co(II) atom is tetra-coordinated by two chloride anions and two N atoms from two monodentate 2-amino-5-methyl-1,3,4-thia-diazole ligands, giving a slightly distorted tetra-hedral stereochemistry [bond angle range about Co = 105.16 (12)-112.50 (10)°]. In the complex, the dihedral angle between the 1,3,4-thia-diazole planes in the two ligands is 72.8 (1)°. There are two intra-molecular N-H⋯Cl inter-actions in the complex unit, while in the crystal, inter-molecular N-H⋯N and N-H⋯Cl hydrogen bonds link these units into a two-dimensional layered structure parallel to (011).

No MeSH data available.