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catena-Poly[[tetra-kis-(hexa-methyl-phospho-ramide-κO)bis-(nitrato-κ(2)O,O')lutetium(III)] [silver(I)-di-μ-sulfido-tungstate(VI)-di-μ-sulfido]].

Zhang J - Acta Crystallogr Sect E Struct Rep Online (2012)

Bottom Line: Together with the two nitrate groups, the cation is monovalent, which leads to the anionic chain having a [WS(4)Ag] repeat unit.The polymeric anionic chain has a distorted linear configuration with W-Ag-W and Ag-W-Ag angles of 161.66 (2) and 153.503 (12)°, respectively.The title complex is isotypic with the Y, Yb, Eu, Nd, La, Dy and Sm analogues.

View Article: PubMed Central - HTML - PubMed

Affiliation: Molecular Materials Research Center, Scientific Research Academy, School of Chemistry and Chemical Engineering, Jiangsu University, Zhenjiang 212013, People's Republic of China.

ABSTRACT
In the title compound, {[Lu(NO(3))(2)(C(6)H(18)N(3)OP)(4)][AgWS(4)]}(n), hexa-methyl-phospho-ramide (hmp), tetra-thio-tungstate, silver iodide and lutetium nitrate were self-assembled, forming an anionic {[AgWS(4)](-)}(n) chain extending parallel to [001]. The Lu(III) atom in the cation is coordinated by eight O atoms from two nitrate groups and four hmp ligands in a distorted square-anti-prismatic geometry. Together with the two nitrate groups, the cation is monovalent, which leads to the anionic chain having a [WS(4)Ag] repeat unit. The polymeric anionic chain has a distorted linear configuration with W-Ag-W and Ag-W-Ag angles of 161.66 (2) and 153.503 (12)°, respectively. The title complex is isotypic with the Y, Yb, Eu, Nd, La, Dy and Sm analogues.

No MeSH data available.


The molecular structure of a portion of the anionic chain in the title compound, with 30% probability displacement ellipsoids, Symmetry code: (i) x, -y + 1/2, z - 1/2.
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Fap2: The molecular structure of a portion of the anionic chain in the title compound, with 30% probability displacement ellipsoids, Symmetry code: (i) x, -y + 1/2, z - 1/2.


catena-Poly[[tetra-kis-(hexa-methyl-phospho-ramide-κO)bis-(nitrato-κ(2)O,O')lutetium(III)] [silver(I)-di-μ-sulfido-tungstate(VI)-di-μ-sulfido]].

Zhang J - Acta Crystallogr Sect E Struct Rep Online (2012)

The molecular structure of a portion of the anionic chain in the title compound, with 30% probability displacement ellipsoids, Symmetry code: (i) x, -y + 1/2, z - 1/2.
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC3379104&req=5

Fap2: The molecular structure of a portion of the anionic chain in the title compound, with 30% probability displacement ellipsoids, Symmetry code: (i) x, -y + 1/2, z - 1/2.
Bottom Line: Together with the two nitrate groups, the cation is monovalent, which leads to the anionic chain having a [WS(4)Ag] repeat unit.The polymeric anionic chain has a distorted linear configuration with W-Ag-W and Ag-W-Ag angles of 161.66 (2) and 153.503 (12)°, respectively.The title complex is isotypic with the Y, Yb, Eu, Nd, La, Dy and Sm analogues.

View Article: PubMed Central - HTML - PubMed

Affiliation: Molecular Materials Research Center, Scientific Research Academy, School of Chemistry and Chemical Engineering, Jiangsu University, Zhenjiang 212013, People's Republic of China.

ABSTRACT
In the title compound, {[Lu(NO(3))(2)(C(6)H(18)N(3)OP)(4)][AgWS(4)]}(n), hexa-methyl-phospho-ramide (hmp), tetra-thio-tungstate, silver iodide and lutetium nitrate were self-assembled, forming an anionic {[AgWS(4)](-)}(n) chain extending parallel to [001]. The Lu(III) atom in the cation is coordinated by eight O atoms from two nitrate groups and four hmp ligands in a distorted square-anti-prismatic geometry. Together with the two nitrate groups, the cation is monovalent, which leads to the anionic chain having a [WS(4)Ag] repeat unit. The polymeric anionic chain has a distorted linear configuration with W-Ag-W and Ag-W-Ag angles of 161.66 (2) and 153.503 (12)°, respectively. The title complex is isotypic with the Y, Yb, Eu, Nd, La, Dy and Sm analogues.

No MeSH data available.