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Poly[[(methanol)(μ(4)-2,4,5,6-tetra-fluoro-benzene-1,3-dicarboxyl-ato)copper(II)] methanol monosolvate].

Yan D, Duan Q - Acta Crystallogr Sect E Struct Rep Online (2012)

Bottom Line: In each ligand, the dihedral angles between the benzene ring and the two carboxyl-ate groups are 80.43 (17) and 62.5 (4)°.Within each SBU, the four carboxyl-ate groups come from four symmetry-equivalent tetra-fluoro-isophthalate ligands.Each tetra-fluoro-isophthalate group connects two SBUs, forming a layered structure .

View Article: PubMed Central - HTML - PubMed

Affiliation: School of Materials Science and Engineering, Changchun University of Science and Technology, Changchun 130022, People's Republic of China.

ABSTRACT
In the title compound, {[Cu(C(8)F(4)O(4))(CH(3)OH)]·CH(3)OH}(n), two Cu(II) atoms are bridged by four carboxyl-ate groups, forming the well known paddle-wheel secondary building unit (SBU) with axial methanol ligands. In each ligand, the dihedral angles between the benzene ring and the two carboxyl-ate groups are 80.43 (17) and 62.5 (4)°. Within each SBU, the four carboxyl-ate groups come from four symmetry-equivalent tetra-fluoro-isophthalate ligands. Each tetra-fluoro-isophthalate group connects two SBUs, forming a layered structure . In the crystal, O-H⋯O hydrogen bonds involving the free and ligated methanol mol-ecules link the mol-ecules into a three-dimensional supra-molecular network.

No MeSH data available.


Related in: MedlinePlus

An ellipsoid plot (30% probability level) of the paddlewheel SBU showing the labelled asymmetric unit. Hydrogen atoms are drawn as small arbitrary spheres.
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Fap1: An ellipsoid plot (30% probability level) of the paddlewheel SBU showing the labelled asymmetric unit. Hydrogen atoms are drawn as small arbitrary spheres.


Poly[[(methanol)(μ(4)-2,4,5,6-tetra-fluoro-benzene-1,3-dicarboxyl-ato)copper(II)] methanol monosolvate].

Yan D, Duan Q - Acta Crystallogr Sect E Struct Rep Online (2012)

An ellipsoid plot (30% probability level) of the paddlewheel SBU showing the labelled asymmetric unit. Hydrogen atoms are drawn as small arbitrary spheres.
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC3379103&req=5

Fap1: An ellipsoid plot (30% probability level) of the paddlewheel SBU showing the labelled asymmetric unit. Hydrogen atoms are drawn as small arbitrary spheres.
Bottom Line: In each ligand, the dihedral angles between the benzene ring and the two carboxyl-ate groups are 80.43 (17) and 62.5 (4)°.Within each SBU, the four carboxyl-ate groups come from four symmetry-equivalent tetra-fluoro-isophthalate ligands.Each tetra-fluoro-isophthalate group connects two SBUs, forming a layered structure .

View Article: PubMed Central - HTML - PubMed

Affiliation: School of Materials Science and Engineering, Changchun University of Science and Technology, Changchun 130022, People's Republic of China.

ABSTRACT
In the title compound, {[Cu(C(8)F(4)O(4))(CH(3)OH)]·CH(3)OH}(n), two Cu(II) atoms are bridged by four carboxyl-ate groups, forming the well known paddle-wheel secondary building unit (SBU) with axial methanol ligands. In each ligand, the dihedral angles between the benzene ring and the two carboxyl-ate groups are 80.43 (17) and 62.5 (4)°. Within each SBU, the four carboxyl-ate groups come from four symmetry-equivalent tetra-fluoro-isophthalate ligands. Each tetra-fluoro-isophthalate group connects two SBUs, forming a layered structure . In the crystal, O-H⋯O hydrogen bonds involving the free and ligated methanol mol-ecules link the mol-ecules into a three-dimensional supra-molecular network.

No MeSH data available.


Related in: MedlinePlus