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9-Amino-acridinium bis-(pyridine-2,6-dicarboxyl-ato-κ(3)O(2),N,O(6))ferrate(III) tetra-hydrate.

Mirzaei M, Eshtiagh-Hosseini H, Eydizadeh E, Yousefi Z, Molčanov K - Acta Crystallogr Sect E Struct Rep Online (2012)

Bottom Line: In the anionic complex, the Fe(III) ion is six-coordinated by two almost perpendicular [dihedral angle = 88.78 (7)°] pyridine-2,6-dicarboxyl-ate ligands in a distorted octa-hedral geometry.These chains are linked by three-membered water clusters.The final three-dimensional network is constructed by numerous inter-molecular O-H⋯O and N-H⋯O inter-actions.

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ABSTRACT
The asymmetric unit of the title compound, (C(13)H(11)N(2))[Fe(C(7)H(3)NO(4))(2)]·4H(2)O, contains a 9-amino-acridinium cation, one anionic complex and four uncoordinated water mol-ecules. In the anionic complex, the Fe(III) ion is six-coordinated by two almost perpendicular [dihedral angle = 88.78 (7)°] pyridine-2,6-dicarboxyl-ate ligands in a distorted octa-hedral geometry. In the crystal, anions are connected into chains along [10-1] by weak C-H⋯O inter-actions, which create ten-membered hydrogen-bonded R(2) (2)(10) rings. These chains are linked by three-membered water clusters. The final three-dimensional network is constructed by numerous inter-molecular O-H⋯O and N-H⋯O inter-actions.

No MeSH data available.


Related in: MedlinePlus

An ORTEP view of the title compound with numbering non-hydrogen atoms with probability 50%.
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Fap1: An ORTEP view of the title compound with numbering non-hydrogen atoms with probability 50%.


9-Amino-acridinium bis-(pyridine-2,6-dicarboxyl-ato-κ(3)O(2),N,O(6))ferrate(III) tetra-hydrate.

Mirzaei M, Eshtiagh-Hosseini H, Eydizadeh E, Yousefi Z, Molčanov K - Acta Crystallogr Sect E Struct Rep Online (2012)

An ORTEP view of the title compound with numbering non-hydrogen atoms with probability 50%.
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC3379098&req=5

Fap1: An ORTEP view of the title compound with numbering non-hydrogen atoms with probability 50%.
Bottom Line: In the anionic complex, the Fe(III) ion is six-coordinated by two almost perpendicular [dihedral angle = 88.78 (7)°] pyridine-2,6-dicarboxyl-ate ligands in a distorted octa-hedral geometry.These chains are linked by three-membered water clusters.The final three-dimensional network is constructed by numerous inter-molecular O-H⋯O and N-H⋯O inter-actions.

View Article: PubMed Central - HTML - PubMed

ABSTRACT
The asymmetric unit of the title compound, (C(13)H(11)N(2))[Fe(C(7)H(3)NO(4))(2)]·4H(2)O, contains a 9-amino-acridinium cation, one anionic complex and four uncoordinated water mol-ecules. In the anionic complex, the Fe(III) ion is six-coordinated by two almost perpendicular [dihedral angle = 88.78 (7)°] pyridine-2,6-dicarboxyl-ate ligands in a distorted octa-hedral geometry. In the crystal, anions are connected into chains along [10-1] by weak C-H⋯O inter-actions, which create ten-membered hydrogen-bonded R(2) (2)(10) rings. These chains are linked by three-membered water clusters. The final three-dimensional network is constructed by numerous inter-molecular O-H⋯O and N-H⋯O inter-actions.

No MeSH data available.


Related in: MedlinePlus