Limits...
A new dabco-templated metal sulfate: 1,4-diazo-niabicyclo-[2.2.2]octane hexa-aqua-cadmium bis-(sulfate).

Wang BQ, Yan HB, Fang CJ, Zhang Z - Acta Crystallogr Sect E Struct Rep Online (2012)

Bottom Line: The title double mol-ecular salt, (C(6)H(14)N(2))[Cd(H(2)O)(6)](SO(4))(2), is an isostructure of its Mn and Co analogues.The Cd(II) atom adopts a near-regular CdO(6) octa-hedral coordination geometry.The crystal structure can be described as an alternation of cationic and anionic layers along [010], and numerous O-H⋯O and N-H⋯O hydrogen bonds are observed.

View Article: PubMed Central - HTML - PubMed

ABSTRACT
The title double mol-ecular salt, (C(6)H(14)N(2))[Cd(H(2)O)(6)](SO(4))(2), is an isostructure of its Mn and Co analogues. The Cd(II) atom adopts a near-regular CdO(6) octa-hedral coordination geometry. The crystal structure can be described as an alternation of cationic and anionic layers along [010], and numerous O-H⋯O and N-H⋯O hydrogen bonds are observed. No thermal anomalies corresponding to possible phase transitions were observed in DSC (differential scanning calorimetry) measurements and the 93 K structure is almost the same as the room-temperature structure.

No MeSH data available.


Related in: MedlinePlus

Neighboring sulfates in the environment of [Cd(H2O)6]2+ in I.
© Copyright Policy - open-access
Related In: Results  -  Collection

License
getmorefigures.php?uid=PMC3379097&req=5

Fap3: Neighboring sulfates in the environment of [Cd(H2O)6]2+ in I.


A new dabco-templated metal sulfate: 1,4-diazo-niabicyclo-[2.2.2]octane hexa-aqua-cadmium bis-(sulfate).

Wang BQ, Yan HB, Fang CJ, Zhang Z - Acta Crystallogr Sect E Struct Rep Online (2012)

Neighboring sulfates in the environment of [Cd(H2O)6]2+ in I.
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC3379097&req=5

Fap3: Neighboring sulfates in the environment of [Cd(H2O)6]2+ in I.
Bottom Line: The title double mol-ecular salt, (C(6)H(14)N(2))[Cd(H(2)O)(6)](SO(4))(2), is an isostructure of its Mn and Co analogues.The Cd(II) atom adopts a near-regular CdO(6) octa-hedral coordination geometry.The crystal structure can be described as an alternation of cationic and anionic layers along [010], and numerous O-H⋯O and N-H⋯O hydrogen bonds are observed.

View Article: PubMed Central - HTML - PubMed

ABSTRACT
The title double mol-ecular salt, (C(6)H(14)N(2))[Cd(H(2)O)(6)](SO(4))(2), is an isostructure of its Mn and Co analogues. The Cd(II) atom adopts a near-regular CdO(6) octa-hedral coordination geometry. The crystal structure can be described as an alternation of cationic and anionic layers along [010], and numerous O-H⋯O and N-H⋯O hydrogen bonds are observed. No thermal anomalies corresponding to possible phase transitions were observed in DSC (differential scanning calorimetry) measurements and the 93 K structure is almost the same as the room-temperature structure.

No MeSH data available.


Related in: MedlinePlus