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Di-μ-iodido-bis-[(dimethyl 2,2'-biquinoline-4,4'-dicarboxyl-ate-κ(2)N,N')copper(I)].

Starosta R, Komarnicka UK, Nagaj J, Stokowa-Sołtys K, Bykowska A - Acta Crystallogr Sect E Struct Rep Online (2012)

Bottom Line: In the centrosymmetric dinuclear title complex, [Cu(2)I(2)(C(22)H(16)N(2)O(4))(2)], the Cu(I) atom is coordinated in a distorted tetra-hedral geometry by an N,N'-bidentate dimethyl 2,2'-biquinoline-4,4'-dicarboxyl-ate ligand and two symmetry-related I atoms, which act as bridges to a symmetry-related Cu(I) atom.The distance between the Cu(I) atoms within the dinuclear unit is 2.6723 (11) Å.

View Article: PubMed Central - HTML - PubMed

Affiliation: Faculty of Chemistry, University of Wrocław, 14 Joliot-Curie St, 50-383 Wrocław, Poland.

ABSTRACT
In the centrosymmetric dinuclear title complex, [Cu(2)I(2)(C(22)H(16)N(2)O(4))(2)], the Cu(I) atom is coordinated in a distorted tetra-hedral geometry by an N,N'-bidentate dimethyl 2,2'-biquinoline-4,4'-dicarboxyl-ate ligand and two symmetry-related I atoms, which act as bridges to a symmetry-related Cu(I) atom. The distance between the Cu(I) atoms within the dinuclear unit is 2.6723 (11) Å.

No MeSH data available.


The molecular structure of the complex showing the atom-labelling scheme and displacement ellipsoids at the 50% probability (symmmetry code used: -x + 1, -y, -z + 1).
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Fap1: The molecular structure of the complex showing the atom-labelling scheme and displacement ellipsoids at the 50% probability (symmmetry code used: -x + 1, -y, -z + 1).


Di-μ-iodido-bis-[(dimethyl 2,2'-biquinoline-4,4'-dicarboxyl-ate-κ(2)N,N')copper(I)].

Starosta R, Komarnicka UK, Nagaj J, Stokowa-Sołtys K, Bykowska A - Acta Crystallogr Sect E Struct Rep Online (2012)

The molecular structure of the complex showing the atom-labelling scheme and displacement ellipsoids at the 50% probability (symmmetry code used: -x + 1, -y, -z + 1).
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC3379095&req=5

Fap1: The molecular structure of the complex showing the atom-labelling scheme and displacement ellipsoids at the 50% probability (symmmetry code used: -x + 1, -y, -z + 1).
Bottom Line: In the centrosymmetric dinuclear title complex, [Cu(2)I(2)(C(22)H(16)N(2)O(4))(2)], the Cu(I) atom is coordinated in a distorted tetra-hedral geometry by an N,N'-bidentate dimethyl 2,2'-biquinoline-4,4'-dicarboxyl-ate ligand and two symmetry-related I atoms, which act as bridges to a symmetry-related Cu(I) atom.The distance between the Cu(I) atoms within the dinuclear unit is 2.6723 (11) Å.

View Article: PubMed Central - HTML - PubMed

Affiliation: Faculty of Chemistry, University of Wrocław, 14 Joliot-Curie St, 50-383 Wrocław, Poland.

ABSTRACT
In the centrosymmetric dinuclear title complex, [Cu(2)I(2)(C(22)H(16)N(2)O(4))(2)], the Cu(I) atom is coordinated in a distorted tetra-hedral geometry by an N,N'-bidentate dimethyl 2,2'-biquinoline-4,4'-dicarboxyl-ate ligand and two symmetry-related I atoms, which act as bridges to a symmetry-related Cu(I) atom. The distance between the Cu(I) atoms within the dinuclear unit is 2.6723 (11) Å.

No MeSH data available.