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Poly[(μ(3)-benzene-1,3-dicarboxyl-ato-κ(4)O(1):O(1'):O(3),O(3'))bis-(pyridine-κN)cobalt(II)].

Xie F, Zhang D, Zhang X - Acta Crystallogr Sect E Struct Rep Online (2012)

Bottom Line: In the asymmetric unit of the title polymeric compound, [Co(C(8)H(4)O(4))(C(5)H(5)N)(2)](n), there are two crystallographically independent Co(II) atoms, each of which is six-coordinated in a distorted octa-hedral geometry by four O atoms from benzene-dicarboxyl-ate anions and two N atoms from pyridine ligands.The benzene-dicarboxyl-ate dianions bridge the Co(II) atoms into a tape running along the b axis.C-H⋯O hydrogen bonds are observed in the tape and between the tapes.

View Article: PubMed Central - HTML - PubMed

Affiliation: School of Environment and Chemical Engineering, Xi'an Polytechnic University, Xi'an 710048, Shaanxi Province, People's Republic of China.

ABSTRACT
In the asymmetric unit of the title polymeric compound, [Co(C(8)H(4)O(4))(C(5)H(5)N)(2)](n), there are two crystallographically independent Co(II) atoms, each of which is six-coordinated in a distorted octa-hedral geometry by four O atoms from benzene-dicarboxyl-ate anions and two N atoms from pyridine ligands. The benzene-dicarboxyl-ate dianions bridge the Co(II) atoms into a tape running along the b axis. C-H⋯O hydrogen bonds are observed in the tape and between the tapes.

No MeSH data available.


Related in: MedlinePlus

A part of the polymeric structure of the title compound. Displacement ellipsoids are drawn at the 25% probability level. [Symmetry codes: (i) x, y - 1, z; (ii) x, y + 1, z.]
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Fap1: A part of the polymeric structure of the title compound. Displacement ellipsoids are drawn at the 25% probability level. [Symmetry codes: (i) x, y - 1, z; (ii) x, y + 1, z.]


Poly[(μ(3)-benzene-1,3-dicarboxyl-ato-κ(4)O(1):O(1'):O(3),O(3'))bis-(pyridine-κN)cobalt(II)].

Xie F, Zhang D, Zhang X - Acta Crystallogr Sect E Struct Rep Online (2012)

A part of the polymeric structure of the title compound. Displacement ellipsoids are drawn at the 25% probability level. [Symmetry codes: (i) x, y - 1, z; (ii) x, y + 1, z.]
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC3379094&req=5

Fap1: A part of the polymeric structure of the title compound. Displacement ellipsoids are drawn at the 25% probability level. [Symmetry codes: (i) x, y - 1, z; (ii) x, y + 1, z.]
Bottom Line: In the asymmetric unit of the title polymeric compound, [Co(C(8)H(4)O(4))(C(5)H(5)N)(2)](n), there are two crystallographically independent Co(II) atoms, each of which is six-coordinated in a distorted octa-hedral geometry by four O atoms from benzene-dicarboxyl-ate anions and two N atoms from pyridine ligands.The benzene-dicarboxyl-ate dianions bridge the Co(II) atoms into a tape running along the b axis.C-H⋯O hydrogen bonds are observed in the tape and between the tapes.

View Article: PubMed Central - HTML - PubMed

Affiliation: School of Environment and Chemical Engineering, Xi'an Polytechnic University, Xi'an 710048, Shaanxi Province, People's Republic of China.

ABSTRACT
In the asymmetric unit of the title polymeric compound, [Co(C(8)H(4)O(4))(C(5)H(5)N)(2)](n), there are two crystallographically independent Co(II) atoms, each of which is six-coordinated in a distorted octa-hedral geometry by four O atoms from benzene-dicarboxyl-ate anions and two N atoms from pyridine ligands. The benzene-dicarboxyl-ate dianions bridge the Co(II) atoms into a tape running along the b axis. C-H⋯O hydrogen bonds are observed in the tape and between the tapes.

No MeSH data available.


Related in: MedlinePlus