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Diaqua-bis-{1-[(1H-benzimidazol-2-yl)meth-yl]-1H-imidazole-κN(3)}dichlorido-cadmium hexa-hydrate.

Xie XN, Lu M, Yuan J, Yang HX - Acta Crystallogr Sect E Struct Rep Online (2012)

Bottom Line: In the title complex, [CdCl(2)(C(11)H(10)N(4))(2)(H(2)O)(2)]·6H(2)O, the Cd(II) atom is located on a twofold rotation axis and is coordinated by two N atoms from two 1-[(1H-benzimidazol-2-yl)meth-yl]-1H-imidazole ligands and two water O atoms in equatorial positions and by two Cl atoms in axial positions, leading to an elongated octa-hedral environment.The two coordinating and two of the lattice water mol-ecules are also located on twofold rotation axes.In the crystal, complex mol-ecules and solvent water mol-ecules are linked through a complex inter-molecular N-H⋯O, O-H⋯N, O-H⋯O and O-H⋯Cl hydrogen-bonding scheme into a three-dimensional network.

View Article: PubMed Central - HTML - PubMed

Affiliation: Pharmacy College, Henan University of Traditional Chinese Medicine, Zhengzhou 450008, People's Republic of China.

ABSTRACT
In the title complex, [CdCl(2)(C(11)H(10)N(4))(2)(H(2)O)(2)]·6H(2)O, the Cd(II) atom is located on a twofold rotation axis and is coordinated by two N atoms from two 1-[(1H-benzimidazol-2-yl)meth-yl]-1H-imidazole ligands and two water O atoms in equatorial positions and by two Cl atoms in axial positions, leading to an elongated octa-hedral environment. The two coordinating and two of the lattice water mol-ecules are also located on twofold rotation axes. In the crystal, complex mol-ecules and solvent water mol-ecules are linked through a complex inter-molecular N-H⋯O, O-H⋯N, O-H⋯O and O-H⋯Cl hydrogen-bonding scheme into a three-dimensional network.

No MeSH data available.


Related in: MedlinePlus

View of the title complex showing labeling and 30% probability displacement ellipsolids. [Symmetry code A: -x + 1, y, -z + 1/2.]
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Fap1: View of the title complex showing labeling and 30% probability displacement ellipsolids. [Symmetry code A: -x + 1, y, -z + 1/2.]


Diaqua-bis-{1-[(1H-benzimidazol-2-yl)meth-yl]-1H-imidazole-κN(3)}dichlorido-cadmium hexa-hydrate.

Xie XN, Lu M, Yuan J, Yang HX - Acta Crystallogr Sect E Struct Rep Online (2012)

View of the title complex showing labeling and 30% probability displacement ellipsolids. [Symmetry code A: -x + 1, y, -z + 1/2.]
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC3379093&req=5

Fap1: View of the title complex showing labeling and 30% probability displacement ellipsolids. [Symmetry code A: -x + 1, y, -z + 1/2.]
Bottom Line: In the title complex, [CdCl(2)(C(11)H(10)N(4))(2)(H(2)O)(2)]·6H(2)O, the Cd(II) atom is located on a twofold rotation axis and is coordinated by two N atoms from two 1-[(1H-benzimidazol-2-yl)meth-yl]-1H-imidazole ligands and two water O atoms in equatorial positions and by two Cl atoms in axial positions, leading to an elongated octa-hedral environment.The two coordinating and two of the lattice water mol-ecules are also located on twofold rotation axes.In the crystal, complex mol-ecules and solvent water mol-ecules are linked through a complex inter-molecular N-H⋯O, O-H⋯N, O-H⋯O and O-H⋯Cl hydrogen-bonding scheme into a three-dimensional network.

View Article: PubMed Central - HTML - PubMed

Affiliation: Pharmacy College, Henan University of Traditional Chinese Medicine, Zhengzhou 450008, People's Republic of China.

ABSTRACT
In the title complex, [CdCl(2)(C(11)H(10)N(4))(2)(H(2)O)(2)]·6H(2)O, the Cd(II) atom is located on a twofold rotation axis and is coordinated by two N atoms from two 1-[(1H-benzimidazol-2-yl)meth-yl]-1H-imidazole ligands and two water O atoms in equatorial positions and by two Cl atoms in axial positions, leading to an elongated octa-hedral environment. The two coordinating and two of the lattice water mol-ecules are also located on twofold rotation axes. In the crystal, complex mol-ecules and solvent water mol-ecules are linked through a complex inter-molecular N-H⋯O, O-H⋯N, O-H⋯O and O-H⋯Cl hydrogen-bonding scheme into a three-dimensional network.

No MeSH data available.


Related in: MedlinePlus