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{4,4',6,6'-Tetra-bromo-2,2'-[2,2-dimethyl-propane-1,3-diylbis(nitrilo-methanylyl-idene)]diphenolato}nickel(II).

Kargar H, Kia R, Tahir MN - Acta Crystallogr Sect E Struct Rep Online (2012)

Bottom Line: The asymmetric unit of the title compound, [Ni(C(19)H(16)Br(4)N(2)O(2))], comprises half of a Schiff base complex.The geometry around the Ni(II) atom, located on a twofold rotation axis, is distorted square-planar, which is supported by the N(2)O(2) donor atoms of the coordinated ligand.The dihedral angle between the substituted benzene rings is 23.19 (17)°.

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ABSTRACT
The asymmetric unit of the title compound, [Ni(C(19)H(16)Br(4)N(2)O(2))], comprises half of a Schiff base complex. The geometry around the Ni(II) atom, located on a twofold rotation axis, is distorted square-planar, which is supported by the N(2)O(2) donor atoms of the coordinated ligand. The dihedral angle between the substituted benzene rings is 23.19 (17)°. In the crystal, a short inter-molecular Br⋯Br [3.6475 (7) Å] inter-action is present.

No MeSH data available.


Related in: MedlinePlus

The crystal packing of the title compound viewed along the c-axis, showing how the molecules are linked via the intermolecular Br···Br interactions (dashed lines) to form chains along the a axis [the H atoms have been omitted for clarity].
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Fap2: The crystal packing of the title compound viewed along the c-axis, showing how the molecules are linked via the intermolecular Br···Br interactions (dashed lines) to form chains along the a axis [the H atoms have been omitted for clarity].


{4,4',6,6'-Tetra-bromo-2,2'-[2,2-dimethyl-propane-1,3-diylbis(nitrilo-methanylyl-idene)]diphenolato}nickel(II).

Kargar H, Kia R, Tahir MN - Acta Crystallogr Sect E Struct Rep Online (2012)

The crystal packing of the title compound viewed along the c-axis, showing how the molecules are linked via the intermolecular Br···Br interactions (dashed lines) to form chains along the a axis [the H atoms have been omitted for clarity].
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC3379092&req=5

Fap2: The crystal packing of the title compound viewed along the c-axis, showing how the molecules are linked via the intermolecular Br···Br interactions (dashed lines) to form chains along the a axis [the H atoms have been omitted for clarity].
Bottom Line: The asymmetric unit of the title compound, [Ni(C(19)H(16)Br(4)N(2)O(2))], comprises half of a Schiff base complex.The geometry around the Ni(II) atom, located on a twofold rotation axis, is distorted square-planar, which is supported by the N(2)O(2) donor atoms of the coordinated ligand.The dihedral angle between the substituted benzene rings is 23.19 (17)°.

View Article: PubMed Central - HTML - PubMed

ABSTRACT
The asymmetric unit of the title compound, [Ni(C(19)H(16)Br(4)N(2)O(2))], comprises half of a Schiff base complex. The geometry around the Ni(II) atom, located on a twofold rotation axis, is distorted square-planar, which is supported by the N(2)O(2) donor atoms of the coordinated ligand. The dihedral angle between the substituted benzene rings is 23.19 (17)°. In the crystal, a short inter-molecular Br⋯Br [3.6475 (7) Å] inter-action is present.

No MeSH data available.


Related in: MedlinePlus