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{4,4',6,6'-Tetra-bromo-2,2'-[2,2-dimethyl-propane-1,3-diylbis(nitrilo-methanylyl-idene)]diphenolato}nickel(II).

Kargar H, Kia R, Tahir MN - Acta Crystallogr Sect E Struct Rep Online (2012)

Bottom Line: The asymmetric unit of the title compound, [Ni(C(19)H(16)Br(4)N(2)O(2))], comprises half of a Schiff base complex.The geometry around the Ni(II) atom, located on a twofold rotation axis, is distorted square-planar, which is supported by the N(2)O(2) donor atoms of the coordinated ligand.The dihedral angle between the substituted benzene rings is 23.19 (17)°.

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ABSTRACT
The asymmetric unit of the title compound, [Ni(C(19)H(16)Br(4)N(2)O(2))], comprises half of a Schiff base complex. The geometry around the Ni(II) atom, located on a twofold rotation axis, is distorted square-planar, which is supported by the N(2)O(2) donor atoms of the coordinated ligand. The dihedral angle between the substituted benzene rings is 23.19 (17)°. In the crystal, a short inter-molecular Br⋯Br [3.6475 (7) Å] inter-action is present.

No MeSH data available.


Related in: MedlinePlus

A view of the molecular structure of the title compound, showing 40% probability displacement ellipsoids and the atomic numbering [symmetry code: (A) = -x, y, -z+1/2].
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Fap1: A view of the molecular structure of the title compound, showing 40% probability displacement ellipsoids and the atomic numbering [symmetry code: (A) = -x, y, -z+1/2].


{4,4',6,6'-Tetra-bromo-2,2'-[2,2-dimethyl-propane-1,3-diylbis(nitrilo-methanylyl-idene)]diphenolato}nickel(II).

Kargar H, Kia R, Tahir MN - Acta Crystallogr Sect E Struct Rep Online (2012)

A view of the molecular structure of the title compound, showing 40% probability displacement ellipsoids and the atomic numbering [symmetry code: (A) = -x, y, -z+1/2].
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC3379092&req=5

Fap1: A view of the molecular structure of the title compound, showing 40% probability displacement ellipsoids and the atomic numbering [symmetry code: (A) = -x, y, -z+1/2].
Bottom Line: The asymmetric unit of the title compound, [Ni(C(19)H(16)Br(4)N(2)O(2))], comprises half of a Schiff base complex.The geometry around the Ni(II) atom, located on a twofold rotation axis, is distorted square-planar, which is supported by the N(2)O(2) donor atoms of the coordinated ligand.The dihedral angle between the substituted benzene rings is 23.19 (17)°.

View Article: PubMed Central - HTML - PubMed

ABSTRACT
The asymmetric unit of the title compound, [Ni(C(19)H(16)Br(4)N(2)O(2))], comprises half of a Schiff base complex. The geometry around the Ni(II) atom, located on a twofold rotation axis, is distorted square-planar, which is supported by the N(2)O(2) donor atoms of the coordinated ligand. The dihedral angle between the substituted benzene rings is 23.19 (17)°. In the crystal, a short inter-molecular Br⋯Br [3.6475 (7) Å] inter-action is present.

No MeSH data available.


Related in: MedlinePlus