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{4,4',6,6'-Tetra-iodo-2,2'-[2,2-dimethyl-propane-1,3-diylbis(nitrilo-methanylyl-idene)]diphenolato}copper(II).

Kargar H, Kia R, Shakarami T, Tahir MN - Acta Crystallogr Sect E Struct Rep Online (2012)

Bottom Line: In the title compound, [Cu(C(19)H(16)I(4)N(2)O(2))], the Cu(II) atom and the substituted C atom of the diamine segment lie on a crystallographic twofold rotation axis.The geometry around the Cu(II) atom is distorted square-planar, which is supported by the N(2)O(2) donor atoms of the coordinated Schiff base.The dihedral angle between the symmetry-related substituted benzene rings is 29.40 (19)°.

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ABSTRACT
In the title compound, [Cu(C(19)H(16)I(4)N(2)O(2))], the Cu(II) atom and the substituted C atom of the diamine segment lie on a crystallographic twofold rotation axis. The geometry around the Cu(II) atom is distorted square-planar, which is supported by the N(2)O(2) donor atoms of the coordinated Schiff base. The dihedral angle between the symmetry-related substituted benzene rings is 29.40 (19)°. In the crystal, a short I⋯I [3.8766 (6) Å] contact is present and links neighbouring mol-ecules into chains propagating along the a axis.

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The crystal packing of the title compound viewed along the c-axis, showing how the molecules are linked via the intermolecular I···I interactions (dashed lines) to form chains along the a axis [the H atoms have been omitted for clarity].
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Fap2: The crystal packing of the title compound viewed along the c-axis, showing how the molecules are linked via the intermolecular I···I interactions (dashed lines) to form chains along the a axis [the H atoms have been omitted for clarity].


{4,4',6,6'-Tetra-iodo-2,2'-[2,2-dimethyl-propane-1,3-diylbis(nitrilo-methanylyl-idene)]diphenolato}copper(II).

Kargar H, Kia R, Shakarami T, Tahir MN - Acta Crystallogr Sect E Struct Rep Online (2012)

The crystal packing of the title compound viewed along the c-axis, showing how the molecules are linked via the intermolecular I···I interactions (dashed lines) to form chains along the a axis [the H atoms have been omitted for clarity].
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC3379091&req=5

Fap2: The crystal packing of the title compound viewed along the c-axis, showing how the molecules are linked via the intermolecular I···I interactions (dashed lines) to form chains along the a axis [the H atoms have been omitted for clarity].
Bottom Line: In the title compound, [Cu(C(19)H(16)I(4)N(2)O(2))], the Cu(II) atom and the substituted C atom of the diamine segment lie on a crystallographic twofold rotation axis.The geometry around the Cu(II) atom is distorted square-planar, which is supported by the N(2)O(2) donor atoms of the coordinated Schiff base.The dihedral angle between the symmetry-related substituted benzene rings is 29.40 (19)°.

View Article: PubMed Central - HTML - PubMed

ABSTRACT
In the title compound, [Cu(C(19)H(16)I(4)N(2)O(2))], the Cu(II) atom and the substituted C atom of the diamine segment lie on a crystallographic twofold rotation axis. The geometry around the Cu(II) atom is distorted square-planar, which is supported by the N(2)O(2) donor atoms of the coordinated Schiff base. The dihedral angle between the symmetry-related substituted benzene rings is 29.40 (19)°. In the crystal, a short I⋯I [3.8766 (6) Å] contact is present and links neighbouring mol-ecules into chains propagating along the a axis.

No MeSH data available.


Related in: MedlinePlus