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Lithium bis-(2-methyl-lactato)borate monohydrate.

Allen JL, Paillard E, Boyle PD, Henderson WA - Acta Crystallogr Sect E Struct Rep Online (2012)

Bottom Line: The lithium cations are pseudo-tetra-hedrally coordinated by three methyl-lactate ligands and a water mol-ecule.The asymmetric units couple across crystallographic inversion centers, forming the 12-membered macrocycles.These macrocycles, in turn, cross-link through the Li(+) cations, forming an infinite polymeric structure in two dimensions parallel to (101).

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ABSTRACT
The title compound {systematic name: poly[[aqua-lithium]-μ-3,3,8,8-tetra-methyl-1,4,6,9-tetra-oxa-5λ(4)-borataspiro-[4.4]nonane-2,7-dione]}, [Li(C(8)H(12)BO(6))(H(2)O)](n) (LiBMLB), forms a 12-membered macrocycle, which lies across a crystallographic inversion center. The lithium cations are pseudo-tetra-hedrally coordinated by three methyl-lactate ligands and a water mol-ecule. The asymmetric units couple across crystallographic inversion centers, forming the 12-membered macrocycles. These macrocycles, in turn, cross-link through the Li(+) cations, forming an infinite polymeric structure in two dimensions parallel to (101).

No MeSH data available.


A 12-membered macrocycle formed from two LiBMLB-H2O units. Thermal ellipsoids are at 50% probability (Li-purple, O-red, B-tan, C-grey).
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Fap2: A 12-membered macrocycle formed from two LiBMLB-H2O units. Thermal ellipsoids are at 50% probability (Li-purple, O-red, B-tan, C-grey).


Lithium bis-(2-methyl-lactato)borate monohydrate.

Allen JL, Paillard E, Boyle PD, Henderson WA - Acta Crystallogr Sect E Struct Rep Online (2012)

A 12-membered macrocycle formed from two LiBMLB-H2O units. Thermal ellipsoids are at 50% probability (Li-purple, O-red, B-tan, C-grey).
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC3379088&req=5

Fap2: A 12-membered macrocycle formed from two LiBMLB-H2O units. Thermal ellipsoids are at 50% probability (Li-purple, O-red, B-tan, C-grey).
Bottom Line: The lithium cations are pseudo-tetra-hedrally coordinated by three methyl-lactate ligands and a water mol-ecule.The asymmetric units couple across crystallographic inversion centers, forming the 12-membered macrocycles.These macrocycles, in turn, cross-link through the Li(+) cations, forming an infinite polymeric structure in two dimensions parallel to (101).

View Article: PubMed Central - HTML - PubMed

ABSTRACT
The title compound {systematic name: poly[[aqua-lithium]-μ-3,3,8,8-tetra-methyl-1,4,6,9-tetra-oxa-5λ(4)-borataspiro-[4.4]nonane-2,7-dione]}, [Li(C(8)H(12)BO(6))(H(2)O)](n) (LiBMLB), forms a 12-membered macrocycle, which lies across a crystallographic inversion center. The lithium cations are pseudo-tetra-hedrally coordinated by three methyl-lactate ligands and a water mol-ecule. The asymmetric units couple across crystallographic inversion centers, forming the 12-membered macrocycles. These macrocycles, in turn, cross-link through the Li(+) cations, forming an infinite polymeric structure in two dimensions parallel to (101).

No MeSH data available.