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N,N'-Dibutyl-N,N,N',N'-tetra-methyl-ethane-1,2-diaminium μ-oxido-bis-[trichloridoferrate(III)].

Närhi SM, Kostamo J, Asikkala J, Oilunkaniemi R, Laitinen RS - Acta Crystallogr Sect E Struct Rep Online (2012)

Bottom Line: The asymmetric unit of the title compound, (C(14)H(34)N(2))[Fe(2)Cl(6)O], contains one complete cation, two half-cations and two anions.The two half-cations are completed by crystallographic inversion symmetry.The Fe(III) atoms adopt fairly regular FeCl(3)O tetra-hedral geometries, although the bridging Fe-O-Fe bond angles differ significantly in the two anions, which both adopt an eclipsed conformation.

View Article: PubMed Central - HTML - PubMed

Affiliation: Department of Chemistry, PO Box 3000, FI-90014 University of Oulu, Finland.

ABSTRACT
The asymmetric unit of the title compound, (C(14)H(34)N(2))[Fe(2)Cl(6)O], contains one complete cation, two half-cations and two anions. The two half-cations are completed by crystallographic inversion symmetry. The Fe(III) atoms adopt fairly regular FeCl(3)O tetra-hedral geometries, although the bridging Fe-O-Fe bond angles differ significantly in the two anions, which both adopt an eclipsed conformation. In the crystal, the components are linked by C-H⋯Cl and C-H⋯O inter-actions.

No MeSH data available.


The molecular structure of the title compound with displacement ellipsoids drawn at 50% probability. Symmetry code: (i) -x + 1, -y + 1, -z + 1; (ii) 1 - x, 1 - y, -z.
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Fap1: The molecular structure of the title compound with displacement ellipsoids drawn at 50% probability. Symmetry code: (i) -x + 1, -y + 1, -z + 1; (ii) 1 - x, 1 - y, -z.


N,N'-Dibutyl-N,N,N',N'-tetra-methyl-ethane-1,2-diaminium μ-oxido-bis-[trichloridoferrate(III)].

Närhi SM, Kostamo J, Asikkala J, Oilunkaniemi R, Laitinen RS - Acta Crystallogr Sect E Struct Rep Online (2012)

The molecular structure of the title compound with displacement ellipsoids drawn at 50% probability. Symmetry code: (i) -x + 1, -y + 1, -z + 1; (ii) 1 - x, 1 - y, -z.
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC3379087&req=5

Fap1: The molecular structure of the title compound with displacement ellipsoids drawn at 50% probability. Symmetry code: (i) -x + 1, -y + 1, -z + 1; (ii) 1 - x, 1 - y, -z.
Bottom Line: The asymmetric unit of the title compound, (C(14)H(34)N(2))[Fe(2)Cl(6)O], contains one complete cation, two half-cations and two anions.The two half-cations are completed by crystallographic inversion symmetry.The Fe(III) atoms adopt fairly regular FeCl(3)O tetra-hedral geometries, although the bridging Fe-O-Fe bond angles differ significantly in the two anions, which both adopt an eclipsed conformation.

View Article: PubMed Central - HTML - PubMed

Affiliation: Department of Chemistry, PO Box 3000, FI-90014 University of Oulu, Finland.

ABSTRACT
The asymmetric unit of the title compound, (C(14)H(34)N(2))[Fe(2)Cl(6)O], contains one complete cation, two half-cations and two anions. The two half-cations are completed by crystallographic inversion symmetry. The Fe(III) atoms adopt fairly regular FeCl(3)O tetra-hedral geometries, although the bridging Fe-O-Fe bond angles differ significantly in the two anions, which both adopt an eclipsed conformation. In the crystal, the components are linked by C-H⋯Cl and C-H⋯O inter-actions.

No MeSH data available.