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Triaqua-1κO,2κ(2)O-bis-(2,2'-bipyridine)-1κ(2)N,N';2κ(2)N,N'-chlorido-1κCl-μ-terephthalato-1:2κ(2)O(1):O(4)-dicopper(II) nitrate monohydrate.

Liu Y, Feng YL, Kuang DZ - Acta Crystallogr Sect E Struct Rep Online (2012)

Bottom Line: One of the Cu(II) ions has a square-pyramidal arrangement, which is defined by a water mol-ecule occupying the apical position, with the equatorial ligators consisting of two N atoms from a 2,2'-bipyridine mol-ecule, one carboxyl-ate O atom from a terephthalate ligand and one O atom from a water mol-ecule.The other Cu(II) ion has a similar coordination environment, except that the apical position is occupied by a chloride ligand instead of a water mol-ecule.An O-H⋯O and O-H⋯Cl hydrogen-bonded three-dimensional network is formed between the components.

View Article: PubMed Central - HTML - PubMed

Affiliation: Key Laboratory of Functional Organometallic Materials, Department of Chemistry and Materials Science, Hengyang Normal University, Hengyang 421008, People's Republic of China.

ABSTRACT
In the binuclear title compound, [Cu(2)(C(8)H(4)O(4))Cl(C(10)H(8)N(2))(2)(H(2)O)(3)]NO(3)·H(2)O, the two crystallographically independent Cu(II) ions have similar coordination environments. One of the Cu(II) ions has a square-pyramidal arrangement, which is defined by a water mol-ecule occupying the apical position, with the equatorial ligators consisting of two N atoms from a 2,2'-bipyridine mol-ecule, one carboxyl-ate O atom from a terephthalate ligand and one O atom from a water mol-ecule. The other Cu(II) ion has a similar coordination environment, except that the apical position is occupied by a chloride ligand instead of a water mol-ecule. An O-H⋯O and O-H⋯Cl hydrogen-bonded three-dimensional network is formed between the components.

No MeSH data available.


Coordination enviroment of Cu in the complex with hydrogen atoms remove d for the clarity. Displacement ellipsoids are drawn at the 30% probability level.
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Fap1: Coordination enviroment of Cu in the complex with hydrogen atoms remove d for the clarity. Displacement ellipsoids are drawn at the 30% probability level.


Triaqua-1κO,2κ(2)O-bis-(2,2'-bipyridine)-1κ(2)N,N';2κ(2)N,N'-chlorido-1κCl-μ-terephthalato-1:2κ(2)O(1):O(4)-dicopper(II) nitrate monohydrate.

Liu Y, Feng YL, Kuang DZ - Acta Crystallogr Sect E Struct Rep Online (2012)

Coordination enviroment of Cu in the complex with hydrogen atoms remove d for the clarity. Displacement ellipsoids are drawn at the 30% probability level.
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC3379086&req=5

Fap1: Coordination enviroment of Cu in the complex with hydrogen atoms remove d for the clarity. Displacement ellipsoids are drawn at the 30% probability level.
Bottom Line: One of the Cu(II) ions has a square-pyramidal arrangement, which is defined by a water mol-ecule occupying the apical position, with the equatorial ligators consisting of two N atoms from a 2,2'-bipyridine mol-ecule, one carboxyl-ate O atom from a terephthalate ligand and one O atom from a water mol-ecule.The other Cu(II) ion has a similar coordination environment, except that the apical position is occupied by a chloride ligand instead of a water mol-ecule.An O-H⋯O and O-H⋯Cl hydrogen-bonded three-dimensional network is formed between the components.

View Article: PubMed Central - HTML - PubMed

Affiliation: Key Laboratory of Functional Organometallic Materials, Department of Chemistry and Materials Science, Hengyang Normal University, Hengyang 421008, People's Republic of China.

ABSTRACT
In the binuclear title compound, [Cu(2)(C(8)H(4)O(4))Cl(C(10)H(8)N(2))(2)(H(2)O)(3)]NO(3)·H(2)O, the two crystallographically independent Cu(II) ions have similar coordination environments. One of the Cu(II) ions has a square-pyramidal arrangement, which is defined by a water mol-ecule occupying the apical position, with the equatorial ligators consisting of two N atoms from a 2,2'-bipyridine mol-ecule, one carboxyl-ate O atom from a terephthalate ligand and one O atom from a water mol-ecule. The other Cu(II) ion has a similar coordination environment, except that the apical position is occupied by a chloride ligand instead of a water mol-ecule. An O-H⋯O and O-H⋯Cl hydrogen-bonded three-dimensional network is formed between the components.

No MeSH data available.