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10-Hy-droxy-benzo[h]quinolin-1-ium tetra-chlorido(pyridine-2-carboxyl-ato-κ(2)N,O)stannate(IV) methanol monosolvate.

Najafi E, Amini MM, Ng SW - Acta Crystallogr Sect E Struct Rep Online (2012)

Bottom Line: The reaction of 4-(dimethyl-amino)-pyridine, picolinic acid and stannic chloride yields the title monosolvated salt, (C(13)H(10)NO)[SnCl(4)(C(6)H(4)NO(2))]·CH(3)OH.The Sn(IV) atom is N,O-chelated by the picolinate ion in a cis-SnNOCl(4) octa-hedral geometry.The cations and anions are linked by weak N-H⋯Cl inter-actions, forming a chain running along the b axis.

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ABSTRACT
The reaction of 4-(dimethyl-amino)-pyridine, picolinic acid and stannic chloride yields the title monosolvated salt, (C(13)H(10)NO)[SnCl(4)(C(6)H(4)NO(2))]·CH(3)OH. The Sn(IV) atom is N,O-chelated by the picolinate ion in a cis-SnNOCl(4) octa-hedral geometry. The cation is linked to the methanol solvent mol-ecule by an O-H⋯O hydrogen bond; the solvent mol-ecule itself is a hydrogen-bond donor to the uncoordinating carboxyl-ate O atom of the anion. The cations and anions are linked by weak N-H⋯Cl inter-actions, forming a chain running along the b axis.

No MeSH data available.


Related in: MedlinePlus

Thermal ellipsoid plot (Barbour, 2001) of (C13H10NO)[SnCl4(C6H4NO2)].CH3OH at the 70% probability level; hydrogen atoms are drawn as spheres of arbitrary radius.
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Fap1: Thermal ellipsoid plot (Barbour, 2001) of (C13H10NO)[SnCl4(C6H4NO2)].CH3OH at the 70% probability level; hydrogen atoms are drawn as spheres of arbitrary radius.


10-Hy-droxy-benzo[h]quinolin-1-ium tetra-chlorido(pyridine-2-carboxyl-ato-κ(2)N,O)stannate(IV) methanol monosolvate.

Najafi E, Amini MM, Ng SW - Acta Crystallogr Sect E Struct Rep Online (2012)

Thermal ellipsoid plot (Barbour, 2001) of (C13H10NO)[SnCl4(C6H4NO2)].CH3OH at the 70% probability level; hydrogen atoms are drawn as spheres of arbitrary radius.
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC3379083&req=5

Fap1: Thermal ellipsoid plot (Barbour, 2001) of (C13H10NO)[SnCl4(C6H4NO2)].CH3OH at the 70% probability level; hydrogen atoms are drawn as spheres of arbitrary radius.
Bottom Line: The reaction of 4-(dimethyl-amino)-pyridine, picolinic acid and stannic chloride yields the title monosolvated salt, (C(13)H(10)NO)[SnCl(4)(C(6)H(4)NO(2))]·CH(3)OH.The Sn(IV) atom is N,O-chelated by the picolinate ion in a cis-SnNOCl(4) octa-hedral geometry.The cations and anions are linked by weak N-H⋯Cl inter-actions, forming a chain running along the b axis.

View Article: PubMed Central - HTML - PubMed

ABSTRACT
The reaction of 4-(dimethyl-amino)-pyridine, picolinic acid and stannic chloride yields the title monosolvated salt, (C(13)H(10)NO)[SnCl(4)(C(6)H(4)NO(2))]·CH(3)OH. The Sn(IV) atom is N,O-chelated by the picolinate ion in a cis-SnNOCl(4) octa-hedral geometry. The cation is linked to the methanol solvent mol-ecule by an O-H⋯O hydrogen bond; the solvent mol-ecule itself is a hydrogen-bond donor to the uncoordinating carboxyl-ate O atom of the anion. The cations and anions are linked by weak N-H⋯Cl inter-actions, forming a chain running along the b axis.

No MeSH data available.


Related in: MedlinePlus