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8-Hy-droxy-2-methyl-quinolinium tetra-chlorido(quinolin-8-olato-κ(2)N,O)stan-nate(IV).

Najafi E, Amini MM, Ng SW - Acta Crystallogr Sect E Struct Rep Online (2012)

Bottom Line: The reaction of 8-hy-droxy-quinoline, 2-methyl-quinolin-8-ol and stannic chloride yields the protonated 8-hy-droxy-2-methyl-quinolinium species.In the title salt, (C(10)H(10)NO)[Sn(C(9)H(6)NO)Cl(4)], the Sn(IV) cation is N,O-chelated by the quinolin-8-olate anion and is further coordinated by four Cl(-) anions in a distorted cis-SnNOCl(4) octa-hedral geometry.In the crystal, the cation is linked to the anion by an O-H⋯O hydrogen bond.

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ABSTRACT
The reaction of 8-hy-droxy-quinoline, 2-methyl-quinolin-8-ol and stannic chloride yields the protonated 8-hy-droxy-2-methyl-quinolinium species. In the title salt, (C(10)H(10)NO)[Sn(C(9)H(6)NO)Cl(4)], the Sn(IV) cation is N,O-chelated by the quinolin-8-olate anion and is further coordinated by four Cl(-) anions in a distorted cis-SnNOCl(4) octa-hedral geometry. In the crystal, the cation is linked to the anion by an O-H⋯O hydrogen bond.

No MeSH data available.


Thermal ellipsoid plot (Barbour, 2001) of (C10H10NO)[SnCl4(C9H6NO)] at the 70% probability level; hydrogen atoms are drawn as spheres of arbitrary radius.
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Fap1: Thermal ellipsoid plot (Barbour, 2001) of (C10H10NO)[SnCl4(C9H6NO)] at the 70% probability level; hydrogen atoms are drawn as spheres of arbitrary radius.


8-Hy-droxy-2-methyl-quinolinium tetra-chlorido(quinolin-8-olato-κ(2)N,O)stan-nate(IV).

Najafi E, Amini MM, Ng SW - Acta Crystallogr Sect E Struct Rep Online (2012)

Thermal ellipsoid plot (Barbour, 2001) of (C10H10NO)[SnCl4(C9H6NO)] at the 70% probability level; hydrogen atoms are drawn as spheres of arbitrary radius.
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC3379079&req=5

Fap1: Thermal ellipsoid plot (Barbour, 2001) of (C10H10NO)[SnCl4(C9H6NO)] at the 70% probability level; hydrogen atoms are drawn as spheres of arbitrary radius.
Bottom Line: The reaction of 8-hy-droxy-quinoline, 2-methyl-quinolin-8-ol and stannic chloride yields the protonated 8-hy-droxy-2-methyl-quinolinium species.In the title salt, (C(10)H(10)NO)[Sn(C(9)H(6)NO)Cl(4)], the Sn(IV) cation is N,O-chelated by the quinolin-8-olate anion and is further coordinated by four Cl(-) anions in a distorted cis-SnNOCl(4) octa-hedral geometry.In the crystal, the cation is linked to the anion by an O-H⋯O hydrogen bond.

View Article: PubMed Central - HTML - PubMed

ABSTRACT
The reaction of 8-hy-droxy-quinoline, 2-methyl-quinolin-8-ol and stannic chloride yields the protonated 8-hy-droxy-2-methyl-quinolinium species. In the title salt, (C(10)H(10)NO)[Sn(C(9)H(6)NO)Cl(4)], the Sn(IV) cation is N,O-chelated by the quinolin-8-olate anion and is further coordinated by four Cl(-) anions in a distorted cis-SnNOCl(4) octa-hedral geometry. In the crystal, the cation is linked to the anion by an O-H⋯O hydrogen bond.

No MeSH data available.