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Bis[(E)-N-(pyridin-3-yl-methyl-idene)hydroxyl-amine-κN(1)]silver(I) perchlorate.

Xu J, Gao S, Ng SW, Tiekink ER - Acta Crystallogr Sect E Struct Rep Online (2012)

Bottom Line: Each of the ions in the title salt, [Ag(C(6)H(6)N(2)O)(2)]ClO(4), is completed by the application of crystallographic twofold symmetry.The Ag(I) atom is coordinated by two pyridine N atoms in an almost linear fashion [N-Ag-N = 170.0 (2)°], with the T-shaped coordination geometry being completed by a weakly associated perchlorate-O atom.The perchlorate O atoms are disordered over two sets of sites in a statistical ratio.

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ABSTRACT
Each of the ions in the title salt, [Ag(C(6)H(6)N(2)O)(2)]ClO(4), is completed by the application of crystallographic twofold symmetry. The Ag(I) atom is coordinated by two pyridine N atoms in an almost linear fashion [N-Ag-N = 170.0 (2)°], with the T-shaped coordination geometry being completed by a weakly associated perchlorate-O atom. Supra-molecular zigzag chains along [100] mediated by O-H⋯N hydrogen bonds [as parts of R(2) (2)(6) loops] feature in the crystal packing. The perchlorate O atoms are disordered over two sets of sites in a statistical ratio.

No MeSH data available.


A view of the zigzag supramolecular chain along [100] in (I). The O—H···N hydrogen bonds are shown as orange dashed lines. Only one orientation for the disordered perchlorate anion is shown.
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Fap2: A view of the zigzag supramolecular chain along [100] in (I). The O—H···N hydrogen bonds are shown as orange dashed lines. Only one orientation for the disordered perchlorate anion is shown.


Bis[(E)-N-(pyridin-3-yl-methyl-idene)hydroxyl-amine-κN(1)]silver(I) perchlorate.

Xu J, Gao S, Ng SW, Tiekink ER - Acta Crystallogr Sect E Struct Rep Online (2012)

A view of the zigzag supramolecular chain along [100] in (I). The O—H···N hydrogen bonds are shown as orange dashed lines. Only one orientation for the disordered perchlorate anion is shown.
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC3379077&req=5

Fap2: A view of the zigzag supramolecular chain along [100] in (I). The O—H···N hydrogen bonds are shown as orange dashed lines. Only one orientation for the disordered perchlorate anion is shown.
Bottom Line: Each of the ions in the title salt, [Ag(C(6)H(6)N(2)O)(2)]ClO(4), is completed by the application of crystallographic twofold symmetry.The Ag(I) atom is coordinated by two pyridine N atoms in an almost linear fashion [N-Ag-N = 170.0 (2)°], with the T-shaped coordination geometry being completed by a weakly associated perchlorate-O atom.The perchlorate O atoms are disordered over two sets of sites in a statistical ratio.

View Article: PubMed Central - HTML - PubMed

ABSTRACT
Each of the ions in the title salt, [Ag(C(6)H(6)N(2)O)(2)]ClO(4), is completed by the application of crystallographic twofold symmetry. The Ag(I) atom is coordinated by two pyridine N atoms in an almost linear fashion [N-Ag-N = 170.0 (2)°], with the T-shaped coordination geometry being completed by a weakly associated perchlorate-O atom. Supra-molecular zigzag chains along [100] mediated by O-H⋯N hydrogen bonds [as parts of R(2) (2)(6) loops] feature in the crystal packing. The perchlorate O atoms are disordered over two sets of sites in a statistical ratio.

No MeSH data available.