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A triclinic polymorph of poly[[bis-[μ-1,2-bis-(pyridin-4-yl)ethene-κ(2)N:N']bis-(thio-cyanato-κN)cobalt(II)] 1,2-bis-(pyridin-4-yl)ethene monosolvate].

Wöhlert S, Jess I, Näther C - Acta Crystallogr Sect E Struct Rep Online (2012)

Bottom Line: The asymmetric unit consists of three crystallographically independent Co(II) cations, six thio-cyanate anions and six coordinating bpe ligands in general positions.Additionally, three non-coordin-ating bpe ligands are present in the asymmetric unit with two of them located on a center of inversion.The Co(II) cations are connected by the bpe ligands into layers parallel to the bc plane.

View Article: PubMed Central - HTML - PubMed

Affiliation: Institut für Anorganische Chemie, Christian-Albrechts-Universität Kiel, Max-Eyth-Strasse 2, 24118 Kiel, Germany.

ABSTRACT
In the crystal structure of the title compound, [Co(NCS)(2)(C(12)H(10)N(2))(2)]·C(12)H(10)N(2), the Co(II) cations are octa-hedrally coordinated by two terminally N-bonded thio-cyanate anions and four 1,2-bis-(pyridin-4-yl)ethene (bpe) ligands. The asymmetric unit consists of three crystallographically independent Co(II) cations, six thio-cyanate anions and six coordinating bpe ligands in general positions. Additionally, three non-coordin-ating bpe ligands are present in the asymmetric unit with two of them located on a center of inversion. The Co(II) cations are connected by the bpe ligands into layers parallel to the bc plane. The crystal investigated was non-merohedrically twinned, with a fractional contribution of 0.261 (2) for the minor domain.

No MeSH data available.


Related in: MedlinePlus

: Crystal structure of the title compound with view approximately along the crystallographic c-axis. The non-coordinated bpe ligands are omitted for clarity.
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Fap5: : Crystal structure of the title compound with view approximately along the crystallographic c-axis. The non-coordinated bpe ligands are omitted for clarity.


A triclinic polymorph of poly[[bis-[μ-1,2-bis-(pyridin-4-yl)ethene-κ(2)N:N']bis-(thio-cyanato-κN)cobalt(II)] 1,2-bis-(pyridin-4-yl)ethene monosolvate].

Wöhlert S, Jess I, Näther C - Acta Crystallogr Sect E Struct Rep Online (2012)

: Crystal structure of the title compound with view approximately along the crystallographic c-axis. The non-coordinated bpe ligands are omitted for clarity.
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC3379076&req=5

Fap5: : Crystal structure of the title compound with view approximately along the crystallographic c-axis. The non-coordinated bpe ligands are omitted for clarity.
Bottom Line: The asymmetric unit consists of three crystallographically independent Co(II) cations, six thio-cyanate anions and six coordinating bpe ligands in general positions.Additionally, three non-coordin-ating bpe ligands are present in the asymmetric unit with two of them located on a center of inversion.The Co(II) cations are connected by the bpe ligands into layers parallel to the bc plane.

View Article: PubMed Central - HTML - PubMed

Affiliation: Institut für Anorganische Chemie, Christian-Albrechts-Universität Kiel, Max-Eyth-Strasse 2, 24118 Kiel, Germany.

ABSTRACT
In the crystal structure of the title compound, [Co(NCS)(2)(C(12)H(10)N(2))(2)]·C(12)H(10)N(2), the Co(II) cations are octa-hedrally coordinated by two terminally N-bonded thio-cyanate anions and four 1,2-bis-(pyridin-4-yl)ethene (bpe) ligands. The asymmetric unit consists of three crystallographically independent Co(II) cations, six thio-cyanate anions and six coordinating bpe ligands in general positions. Additionally, three non-coordin-ating bpe ligands are present in the asymmetric unit with two of them located on a center of inversion. The Co(II) cations are connected by the bpe ligands into layers parallel to the bc plane. The crystal investigated was non-merohedrically twinned, with a fractional contribution of 0.261 (2) for the minor domain.

No MeSH data available.


Related in: MedlinePlus