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(μ-Naphthalene-1,5-disulfonato-κ(2)O(1):O(5))bis-[triaqua-(glycinato-κ(2)N,O)copper(II)].

Gao S, Ng SW - Acta Crystallogr Sect E Struct Rep Online (2012)

Bottom Line: In the title compound, [Cu(2)(C(2)H(4)NO(2))(2)(C(10)H(6)O(6)S(2))(H(2)O)(6)], the naphthalene-disulfonate group lies on a center of inversion and bridges two glycinate-chelated Cu(II) atoms.The Cu(II) atom exists in a CuNO(4) square-pyramidal geometry that is distorted towards an octa-hedron owing to a long Cu-O(sulfonate) bond [2.636 (2) Å].In the crystal, extensive N-H⋯O and O-H⋯O hydrogen bonds link adjacent mol-ecules into a three-dimensional network.

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ABSTRACT
In the title compound, [Cu(2)(C(2)H(4)NO(2))(2)(C(10)H(6)O(6)S(2))(H(2)O)(6)], the naphthalene-disulfonate group lies on a center of inversion and bridges two glycinate-chelated Cu(II) atoms. The Cu(II) atom exists in a CuNO(4) square-pyramidal geometry that is distorted towards an octa-hedron owing to a long Cu-O(sulfonate) bond [2.636 (2) Å]. In the crystal, extensive N-H⋯O and O-H⋯O hydrogen bonds link adjacent mol-ecules into a three-dimensional network.

No MeSH data available.


Thermal ellipsoid plot (Barbour, 2001) of the title compound at the 70% probability level; hydrogen atoms are drawn as spheres of arbitrary radius. Symmetry-related atoms are not labeled.
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Fap1: Thermal ellipsoid plot (Barbour, 2001) of the title compound at the 70% probability level; hydrogen atoms are drawn as spheres of arbitrary radius. Symmetry-related atoms are not labeled.


(μ-Naphthalene-1,5-disulfonato-κ(2)O(1):O(5))bis-[triaqua-(glycinato-κ(2)N,O)copper(II)].

Gao S, Ng SW - Acta Crystallogr Sect E Struct Rep Online (2012)

Thermal ellipsoid plot (Barbour, 2001) of the title compound at the 70% probability level; hydrogen atoms are drawn as spheres of arbitrary radius. Symmetry-related atoms are not labeled.
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC3379073&req=5

Fap1: Thermal ellipsoid plot (Barbour, 2001) of the title compound at the 70% probability level; hydrogen atoms are drawn as spheres of arbitrary radius. Symmetry-related atoms are not labeled.
Bottom Line: In the title compound, [Cu(2)(C(2)H(4)NO(2))(2)(C(10)H(6)O(6)S(2))(H(2)O)(6)], the naphthalene-disulfonate group lies on a center of inversion and bridges two glycinate-chelated Cu(II) atoms.The Cu(II) atom exists in a CuNO(4) square-pyramidal geometry that is distorted towards an octa-hedron owing to a long Cu-O(sulfonate) bond [2.636 (2) Å].In the crystal, extensive N-H⋯O and O-H⋯O hydrogen bonds link adjacent mol-ecules into a three-dimensional network.

View Article: PubMed Central - HTML - PubMed

ABSTRACT
In the title compound, [Cu(2)(C(2)H(4)NO(2))(2)(C(10)H(6)O(6)S(2))(H(2)O)(6)], the naphthalene-disulfonate group lies on a center of inversion and bridges two glycinate-chelated Cu(II) atoms. The Cu(II) atom exists in a CuNO(4) square-pyramidal geometry that is distorted towards an octa-hedron owing to a long Cu-O(sulfonate) bond [2.636 (2) Å]. In the crystal, extensive N-H⋯O and O-H⋯O hydrogen bonds link adjacent mol-ecules into a three-dimensional network.

No MeSH data available.