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catena-Poly[[(2,9-dimethyl-1,10-phenanthroline-κ(2)N,N')lead(II)]-di-μ-bromido].

Sabour B, Najafi E, Amini MM, Ng SW - Acta Crystallogr Sect E Struct Rep Online (2012)

Bottom Line: The N-heterocycle-chelated Pb(II) atom exists in a distorted octa-hedral geometry owing to two long Pb⋯Br inter-actions [2.9562 (5) and 3.2594 (5) Å].These result in a zigzag chain running along the c axis.The lone pair is stereochemically inactive.

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ABSTRACT
In the title compound, [PbBr(2)(C(14)H(12)N(2))](n), the Pb(II) atom lies on a twofold rotation axis. The N-heterocycle-chelated Pb(II) atom exists in a distorted octa-hedral geometry owing to two long Pb⋯Br inter-actions [2.9562 (5) and 3.2594 (5) Å]. These result in a zigzag chain running along the c axis. The lone pair is stereochemically inactive.

No MeSH data available.


Related in: MedlinePlus

Anisotropic displacement ellipsoid plot (Barbour, 2001) of PbBr2(C14H12N2) at the 70% probability level; hydrogen atoms are drawn as spheres of arbitrary radius; symmetry-related atoms are not labeled. Adjacent molecules are linked by a weak Pb···Br bond, which is denoted as a dashed line.
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Fap1: Anisotropic displacement ellipsoid plot (Barbour, 2001) of PbBr2(C14H12N2) at the 70% probability level; hydrogen atoms are drawn as spheres of arbitrary radius; symmetry-related atoms are not labeled. Adjacent molecules are linked by a weak Pb···Br bond, which is denoted as a dashed line.


catena-Poly[[(2,9-dimethyl-1,10-phenanthroline-κ(2)N,N')lead(II)]-di-μ-bromido].

Sabour B, Najafi E, Amini MM, Ng SW - Acta Crystallogr Sect E Struct Rep Online (2012)

Anisotropic displacement ellipsoid plot (Barbour, 2001) of PbBr2(C14H12N2) at the 70% probability level; hydrogen atoms are drawn as spheres of arbitrary radius; symmetry-related atoms are not labeled. Adjacent molecules are linked by a weak Pb···Br bond, which is denoted as a dashed line.
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC3379072&req=5

Fap1: Anisotropic displacement ellipsoid plot (Barbour, 2001) of PbBr2(C14H12N2) at the 70% probability level; hydrogen atoms are drawn as spheres of arbitrary radius; symmetry-related atoms are not labeled. Adjacent molecules are linked by a weak Pb···Br bond, which is denoted as a dashed line.
Bottom Line: The N-heterocycle-chelated Pb(II) atom exists in a distorted octa-hedral geometry owing to two long Pb⋯Br inter-actions [2.9562 (5) and 3.2594 (5) Å].These result in a zigzag chain running along the c axis.The lone pair is stereochemically inactive.

View Article: PubMed Central - HTML - PubMed

ABSTRACT
In the title compound, [PbBr(2)(C(14)H(12)N(2))](n), the Pb(II) atom lies on a twofold rotation axis. The N-heterocycle-chelated Pb(II) atom exists in a distorted octa-hedral geometry owing to two long Pb⋯Br inter-actions [2.9562 (5) and 3.2594 (5) Å]. These result in a zigzag chain running along the c axis. The lone pair is stereochemically inactive.

No MeSH data available.


Related in: MedlinePlus