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Bis{benzyl 2-[4-(4-meth-oxy-phen-yl)butan-2-yl-idene]hydrazinecarbodithio-ato-κ(2)N(2),S}nickel(II).

Tan MY, Ravoof TB, Tahir MI, Crouse KA, Tiekink ER - Acta Crystallogr Sect E Struct Rep Online (2012)

Bottom Line: The Ni(II) atom is N,S-chelated by two hydrazinecarbodithio-ate ligands, which provide an N(2)S(2) donor set that defines a distorted square-planar geometry, the S atoms being approximately cis.The conformation of the chelate ring is an envelope with the Ni(II) atom being the flap atom.The dihedral angle between the least-squares planes through the chelate rings = 30.10 (6)°.

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ABSTRACT
The complete mol-ecule of the title complex, [Ni(C(19)H(21)N(2)OS(2))(2)], is generated by the application of twofold symmetry. The Ni(II) atom is N,S-chelated by two hydrazinecarbodithio-ate ligands, which provide an N(2)S(2) donor set that defines a distorted square-planar geometry, the S atoms being approximately cis. The conformation of the chelate ring is an envelope with the Ni(II) atom being the flap atom. The dihedral angle between the least-squares planes through the chelate rings = 30.10 (6)°. Supra-molecular chains propagated by glide symmetry along the c axis and mediated by C-H⋯N contacts feature in the crystal packing.

No MeSH data available.


Related in: MedlinePlus

A view of the supramolecular chain in (I) mediated by C—H···N interactions, shown as blue dashed lines. Hydrogen atoms not involved in these interactions are omitted.
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Fap2: A view of the supramolecular chain in (I) mediated by C—H···N interactions, shown as blue dashed lines. Hydrogen atoms not involved in these interactions are omitted.


Bis{benzyl 2-[4-(4-meth-oxy-phen-yl)butan-2-yl-idene]hydrazinecarbodithio-ato-κ(2)N(2),S}nickel(II).

Tan MY, Ravoof TB, Tahir MI, Crouse KA, Tiekink ER - Acta Crystallogr Sect E Struct Rep Online (2012)

A view of the supramolecular chain in (I) mediated by C—H···N interactions, shown as blue dashed lines. Hydrogen atoms not involved in these interactions are omitted.
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC3379070&req=5

Fap2: A view of the supramolecular chain in (I) mediated by C—H···N interactions, shown as blue dashed lines. Hydrogen atoms not involved in these interactions are omitted.
Bottom Line: The Ni(II) atom is N,S-chelated by two hydrazinecarbodithio-ate ligands, which provide an N(2)S(2) donor set that defines a distorted square-planar geometry, the S atoms being approximately cis.The conformation of the chelate ring is an envelope with the Ni(II) atom being the flap atom.The dihedral angle between the least-squares planes through the chelate rings = 30.10 (6)°.

View Article: PubMed Central - HTML - PubMed

ABSTRACT
The complete mol-ecule of the title complex, [Ni(C(19)H(21)N(2)OS(2))(2)], is generated by the application of twofold symmetry. The Ni(II) atom is N,S-chelated by two hydrazinecarbodithio-ate ligands, which provide an N(2)S(2) donor set that defines a distorted square-planar geometry, the S atoms being approximately cis. The conformation of the chelate ring is an envelope with the Ni(II) atom being the flap atom. The dihedral angle between the least-squares planes through the chelate rings = 30.10 (6)°. Supra-molecular chains propagated by glide symmetry along the c axis and mediated by C-H⋯N contacts feature in the crystal packing.

No MeSH data available.


Related in: MedlinePlus