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catena-Poly[[[bis-(acetato-κ(2)O,O')aqua-cadmium]-μ-[(pyridin-3-yl)(pyridin-4-yl)methanone]-κ(2)N:N'] dihydrate].

Wang ZW, Li AM, Zhang Y - Acta Crystallogr Sect E Struct Rep Online (2012)

Bottom Line: In the title complex, {[Cd(CH(3)COO)(2)(C(11)H(8)N(2)O)(H(2)O)]·2H(2)O}(n), the Cd(II) ion adopts an O(5)N(2) penta-gonal-bipyramidal coordination geometry with four acetate O atoms and one water O atom at the equatorial sites and two pyridine N atoms at the axial sites.The (pyridin-3-yl)(pyridin-4-yl)methanone ligand acts in a μ(2)-bridging mode, linking the metal atoms, leading to an infinite chain along [-110].O-H⋯O hydrogen bonds involving the lattice water mol-ecules connect these chains into a three-dimensional network.

View Article: PubMed Central - HTML - PubMed

Affiliation: Department of Chemistry, Capital Normal University, Beijing 100048, People's Republic of China.

ABSTRACT
In the title complex, {[Cd(CH(3)COO)(2)(C(11)H(8)N(2)O)(H(2)O)]·2H(2)O}(n), the Cd(II) ion adopts an O(5)N(2) penta-gonal-bipyramidal coordination geometry with four acetate O atoms and one water O atom at the equatorial sites and two pyridine N atoms at the axial sites. The (pyridin-3-yl)(pyridin-4-yl)methanone ligand acts in a μ(2)-bridging mode, linking the metal atoms, leading to an infinite chain along [-110]. O-H⋯O hydrogen bonds involving the lattice water mol-ecules connect these chains into a three-dimensional network.

No MeSH data available.


Infinite chain structure along the [-1 1 0] direction of the title complex.The O atoms of the water were shown as red balls, and all aryl H atoms are omitted for clarity.
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Fap2: Infinite chain structure along the [-1 1 0] direction of the title complex.The O atoms of the water were shown as red balls, and all aryl H atoms are omitted for clarity.


catena-Poly[[[bis-(acetato-κ(2)O,O')aqua-cadmium]-μ-[(pyridin-3-yl)(pyridin-4-yl)methanone]-κ(2)N:N'] dihydrate].

Wang ZW, Li AM, Zhang Y - Acta Crystallogr Sect E Struct Rep Online (2012)

Infinite chain structure along the [-1 1 0] direction of the title complex.The O atoms of the water were shown as red balls, and all aryl H atoms are omitted for clarity.
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC3379068&req=5

Fap2: Infinite chain structure along the [-1 1 0] direction of the title complex.The O atoms of the water were shown as red balls, and all aryl H atoms are omitted for clarity.
Bottom Line: In the title complex, {[Cd(CH(3)COO)(2)(C(11)H(8)N(2)O)(H(2)O)]·2H(2)O}(n), the Cd(II) ion adopts an O(5)N(2) penta-gonal-bipyramidal coordination geometry with four acetate O atoms and one water O atom at the equatorial sites and two pyridine N atoms at the axial sites.The (pyridin-3-yl)(pyridin-4-yl)methanone ligand acts in a μ(2)-bridging mode, linking the metal atoms, leading to an infinite chain along [-110].O-H⋯O hydrogen bonds involving the lattice water mol-ecules connect these chains into a three-dimensional network.

View Article: PubMed Central - HTML - PubMed

Affiliation: Department of Chemistry, Capital Normal University, Beijing 100048, People's Republic of China.

ABSTRACT
In the title complex, {[Cd(CH(3)COO)(2)(C(11)H(8)N(2)O)(H(2)O)]·2H(2)O}(n), the Cd(II) ion adopts an O(5)N(2) penta-gonal-bipyramidal coordination geometry with four acetate O atoms and one water O atom at the equatorial sites and two pyridine N atoms at the axial sites. The (pyridin-3-yl)(pyridin-4-yl)methanone ligand acts in a μ(2)-bridging mode, linking the metal atoms, leading to an infinite chain along [-110]. O-H⋯O hydrogen bonds involving the lattice water mol-ecules connect these chains into a three-dimensional network.

No MeSH data available.