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catena-Poly[[[diaqua-(1,10-phenanthroline-κ(2)N,N')zinc]-μ-4-hy-droxy-3-sulfonato-benzoato-κ(2)O(3):O(1)] sesquihydrate].

Fang XQ, Gao S, Ng SW - Acta Crystallogr Sect E Struct Rep Online (2012)

Bottom Line: The 1,10-phenanthroline-chelated Zn atom in the polymeric title compound, {[Zn(C(7)H(4)O(6)S)(C(12)H(8)N(2))(H(2)O)(2)]·1.5H(2)O}(n), is connected to the sulfonate O atom of one 4-hy-droxy-3-sulfonato-benzoate dianion and to the carboxyl-ate O atom of another dianion.It is also coordinated by two water mol-ecules in an overall octa-hedral environment.The dianion links adjacent metal atoms into a chain running along [110].

View Article: PubMed Central - HTML - PubMed

ABSTRACT
The 1,10-phenanthroline-chelated Zn atom in the polymeric title compound, {[Zn(C(7)H(4)O(6)S)(C(12)H(8)N(2))(H(2)O)(2)]·1.5H(2)O}(n), is connected to the sulfonate O atom of one 4-hy-droxy-3-sulfonato-benzoate dianion and to the carboxyl-ate O atom of another dianion. It is also coordinated by two water mol-ecules in an overall octa-hedral environment. The dianion links adjacent metal atoms into a chain running along [110]. The chains are linked by O-H⋯O hydrogen bonds into a three-dimensional network.

No MeSH data available.


Anisotropic displacement ellipsoid plot (Barbour, 2001) of a portion of the structure of polymeric [Zn(H2O)2(C12H8N2)(C7H4O6S)]n.1.5nH2O at the 50% probability level; hydrogen atoms are drawn as spheres of arbitrary radius.
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Fap1: Anisotropic displacement ellipsoid plot (Barbour, 2001) of a portion of the structure of polymeric [Zn(H2O)2(C12H8N2)(C7H4O6S)]n.1.5nH2O at the 50% probability level; hydrogen atoms are drawn as spheres of arbitrary radius.


catena-Poly[[[diaqua-(1,10-phenanthroline-κ(2)N,N')zinc]-μ-4-hy-droxy-3-sulfonato-benzoato-κ(2)O(3):O(1)] sesquihydrate].

Fang XQ, Gao S, Ng SW - Acta Crystallogr Sect E Struct Rep Online (2012)

Anisotropic displacement ellipsoid plot (Barbour, 2001) of a portion of the structure of polymeric [Zn(H2O)2(C12H8N2)(C7H4O6S)]n.1.5nH2O at the 50% probability level; hydrogen atoms are drawn as spheres of arbitrary radius.
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC3379067&req=5

Fap1: Anisotropic displacement ellipsoid plot (Barbour, 2001) of a portion of the structure of polymeric [Zn(H2O)2(C12H8N2)(C7H4O6S)]n.1.5nH2O at the 50% probability level; hydrogen atoms are drawn as spheres of arbitrary radius.
Bottom Line: The 1,10-phenanthroline-chelated Zn atom in the polymeric title compound, {[Zn(C(7)H(4)O(6)S)(C(12)H(8)N(2))(H(2)O)(2)]·1.5H(2)O}(n), is connected to the sulfonate O atom of one 4-hy-droxy-3-sulfonato-benzoate dianion and to the carboxyl-ate O atom of another dianion.It is also coordinated by two water mol-ecules in an overall octa-hedral environment.The dianion links adjacent metal atoms into a chain running along [110].

View Article: PubMed Central - HTML - PubMed

ABSTRACT
The 1,10-phenanthroline-chelated Zn atom in the polymeric title compound, {[Zn(C(7)H(4)O(6)S)(C(12)H(8)N(2))(H(2)O)(2)]·1.5H(2)O}(n), is connected to the sulfonate O atom of one 4-hy-droxy-3-sulfonato-benzoate dianion and to the carboxyl-ate O atom of another dianion. It is also coordinated by two water mol-ecules in an overall octa-hedral environment. The dianion links adjacent metal atoms into a chain running along [110]. The chains are linked by O-H⋯O hydrogen bonds into a three-dimensional network.

No MeSH data available.