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catena-Poly[[(tetra-aqua-cadmium)-μ-4,4'-bipyridine-κ(2)N:N'] 4-hy-droxy-3-sulfonato-benzoate monohydrate].

Gao S, Ng SW - Acta Crystallogr Sect E Struct Rep Online (2012)

Bottom Line: The two independent Cd(II) atoms in the polymeric title compound, [Cd(C(10)H(8)N(2))(H(2)O)(4)](C(7)H(4)O(6)S)·H(2)O, lie on twofold rotation axes, and each is coordinated by four water mol-ecules and the N atoms of two 4,4'-bipyridine mol-ecules in an octa-hedral geometry.Bridging gives rise to chains along [101] and [-101].The 4-hy-droxy-3-sulfonato-benzoate dianions are not connected to the Cd(II) atoms, but form hydrogen bonds to the coordinated water mol-ecules as well as the lattice water mol-ecule, generating a three-dimensional network.

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ABSTRACT
The two independent Cd(II) atoms in the polymeric title compound, [Cd(C(10)H(8)N(2))(H(2)O)(4)](C(7)H(4)O(6)S)·H(2)O, lie on twofold rotation axes, and each is coordinated by four water mol-ecules and the N atoms of two 4,4'-bipyridine mol-ecules in an octa-hedral geometry. Bridging gives rise to chains along [101] and [-101]. The 4-hy-droxy-3-sulfonato-benzoate dianions are not connected to the Cd(II) atoms, but form hydrogen bonds to the coordinated water mol-ecules as well as the lattice water mol-ecule, generating a three-dimensional network.

No MeSH data available.


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Anisotropic displacement ellipsoid plot (Barbour, 2001) of a portion of the structure of polymeric [Cd(H2O)4(C10H8N2)]2+.(C7H4O6S)2–.H2O at the 70% probability level; hydrogen atoms are drawn as spheres of arbitrary radius.
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Fap1: Anisotropic displacement ellipsoid plot (Barbour, 2001) of a portion of the structure of polymeric [Cd(H2O)4(C10H8N2)]2+.(C7H4O6S)2–.H2O at the 70% probability level; hydrogen atoms are drawn as spheres of arbitrary radius.


catena-Poly[[(tetra-aqua-cadmium)-μ-4,4'-bipyridine-κ(2)N:N'] 4-hy-droxy-3-sulfonato-benzoate monohydrate].

Gao S, Ng SW - Acta Crystallogr Sect E Struct Rep Online (2012)

Anisotropic displacement ellipsoid plot (Barbour, 2001) of a portion of the structure of polymeric [Cd(H2O)4(C10H8N2)]2+.(C7H4O6S)2–.H2O at the 70% probability level; hydrogen atoms are drawn as spheres of arbitrary radius.
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC3379062&req=5

Fap1: Anisotropic displacement ellipsoid plot (Barbour, 2001) of a portion of the structure of polymeric [Cd(H2O)4(C10H8N2)]2+.(C7H4O6S)2–.H2O at the 70% probability level; hydrogen atoms are drawn as spheres of arbitrary radius.
Bottom Line: The two independent Cd(II) atoms in the polymeric title compound, [Cd(C(10)H(8)N(2))(H(2)O)(4)](C(7)H(4)O(6)S)·H(2)O, lie on twofold rotation axes, and each is coordinated by four water mol-ecules and the N atoms of two 4,4'-bipyridine mol-ecules in an octa-hedral geometry.Bridging gives rise to chains along [101] and [-101].The 4-hy-droxy-3-sulfonato-benzoate dianions are not connected to the Cd(II) atoms, but form hydrogen bonds to the coordinated water mol-ecules as well as the lattice water mol-ecule, generating a three-dimensional network.

View Article: PubMed Central - HTML - PubMed

ABSTRACT
The two independent Cd(II) atoms in the polymeric title compound, [Cd(C(10)H(8)N(2))(H(2)O)(4)](C(7)H(4)O(6)S)·H(2)O, lie on twofold rotation axes, and each is coordinated by four water mol-ecules and the N atoms of two 4,4'-bipyridine mol-ecules in an octa-hedral geometry. Bridging gives rise to chains along [101] and [-101]. The 4-hy-droxy-3-sulfonato-benzoate dianions are not connected to the Cd(II) atoms, but form hydrogen bonds to the coordinated water mol-ecules as well as the lattice water mol-ecule, generating a three-dimensional network.

No MeSH data available.


Related in: MedlinePlus