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Bis(2,2'-bipyridyl-κ(2)N,N')dichlorido-rhodium(III) perchlorate.

Dikhtiarenko A, Torre-Fernández L, García-Granda S, García JR, Gimeno J - Acta Crystallogr Sect E Struct Rep Online (2012)

Bottom Line: The Cl ligands are cis.In the crystal, mol-ecules are linked together by a hydrogen-bond network involving the H atoms of bipyridyl rings and perchlorate anions.An O atom of the perchlorate anion is disordered over two sites, with an occupancy-factor ratio of 0.78 (3):0.22 (3).

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ABSTRACT
The asymmetric unit of the title compound, [RhCl(2)(C(10)H(8)N(2))(2)]ClO(4), consists of one unit of the cationic complex [RhCl(2)(bipy)(2)](+) and one uncoordinated perchlorate anion. The Rh(III) atom is coordinated by four N atoms from two bipyridyl ligands and two Cl atoms, forming a distorted octa-hedral environment. The Cl ligands are cis. Two intramolecular C-H⋯Cl hydrogen bonds occur in the cationic complex . In the crystal, mol-ecules are linked together by a hydrogen-bond network involving the H atoms of bipyridyl rings and perchlorate anions. An O atom of the perchlorate anion is disordered over two sites, with an occupancy-factor ratio of 0.78 (3):0.22 (3).

No MeSH data available.


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A view of [RhCl2(C10H8N2)2]ClO4 asymmetric unit. Displacement ellipsoids are drawn at the 50% probability level.
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Fap1: A view of [RhCl2(C10H8N2)2]ClO4 asymmetric unit. Displacement ellipsoids are drawn at the 50% probability level.


Bis(2,2'-bipyridyl-κ(2)N,N')dichlorido-rhodium(III) perchlorate.

Dikhtiarenko A, Torre-Fernández L, García-Granda S, García JR, Gimeno J - Acta Crystallogr Sect E Struct Rep Online (2012)

A view of [RhCl2(C10H8N2)2]ClO4 asymmetric unit. Displacement ellipsoids are drawn at the 50% probability level.
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC3379061&req=5

Fap1: A view of [RhCl2(C10H8N2)2]ClO4 asymmetric unit. Displacement ellipsoids are drawn at the 50% probability level.
Bottom Line: The Cl ligands are cis.In the crystal, mol-ecules are linked together by a hydrogen-bond network involving the H atoms of bipyridyl rings and perchlorate anions.An O atom of the perchlorate anion is disordered over two sites, with an occupancy-factor ratio of 0.78 (3):0.22 (3).

View Article: PubMed Central - HTML - PubMed

ABSTRACT
The asymmetric unit of the title compound, [RhCl(2)(C(10)H(8)N(2))(2)]ClO(4), consists of one unit of the cationic complex [RhCl(2)(bipy)(2)](+) and one uncoordinated perchlorate anion. The Rh(III) atom is coordinated by four N atoms from two bipyridyl ligands and two Cl atoms, forming a distorted octa-hedral environment. The Cl ligands are cis. Two intramolecular C-H⋯Cl hydrogen bonds occur in the cationic complex . In the crystal, mol-ecules are linked together by a hydrogen-bond network involving the H atoms of bipyridyl rings and perchlorate anions. An O atom of the perchlorate anion is disordered over two sites, with an occupancy-factor ratio of 0.78 (3):0.22 (3).

No MeSH data available.


Related in: MedlinePlus