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Bis[hexa-amminecobalt(III)] penta-chloride nitrate.

Wu Q, Du C, Lv Y, Chen G, Pan Q - Acta Crystallogr Sect E Struct Rep Online (2012)

Bottom Line: All Co(3+) ions are six-coordinated by NH(3) mol-ecules, forming [Co(NH(3))(6)](3+) octahedra, with Co-N distances in the range 1.945 (4)-1.967 (3) Å.The nitrate N atom and one of the O atoms lie at a mirror plane.Among the Cl(-) anions, one lies in a general position, one on a twofold axis and two on a mirror plane.

View Article: PubMed Central - HTML - PubMed

Affiliation: Department of Materials and Chemical Engineering, Ministry of Education Key Laboratory of Advanced Materials of Tropical Island Resources, Hainan University, Haikou 570228, People's Republic of China.

ABSTRACT
The title compound, [Co(NH(3))(6)](2)Cl(5)(NO(3)), was obtained under hydro-thermal conditions. The asymmetric unit contains three Co(3+) ions, one lying on an inversion center and the other two located at 2/m positions. All Co(3+) ions are six-coordinated by NH(3) mol-ecules, forming [Co(NH(3))(6)](3+) octahedra, with Co-N distances in the range 1.945 (4)-1.967 (3) Å. The nitrate N atom and one of the O atoms lie at a mirror plane. Among the Cl(-) anions, one lies in a general position, one on a twofold axis and two on a mirror plane. N-H⋯O and N-H⋯Cl hydrogen bonds link the cations and anions into a three-dimensional network.

No MeSH data available.


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A view of the asymmetric unit of title compound showing the atom labelling scheme. Ellipsoids are drawn at the 30% probability level. [Symmetry codes: (i) -x, 1 - y, -z; (ii) -x, y, -z; (iii) x, 1 - y, z; (iv) 1 - x, 1 - y, -z; (v) 1 - x, y, -z; (vi) 1/2 - x, 1/2 - y, 1 - z]. (iv) x, -y + 1, z; (v) -x, -y + 1, -z; (vi) -x, y, -z.
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Fap1: A view of the asymmetric unit of title compound showing the atom labelling scheme. Ellipsoids are drawn at the 30% probability level. [Symmetry codes: (i) -x, 1 - y, -z; (ii) -x, y, -z; (iii) x, 1 - y, z; (iv) 1 - x, 1 - y, -z; (v) 1 - x, y, -z; (vi) 1/2 - x, 1/2 - y, 1 - z]. (iv) x, -y + 1, z; (v) -x, -y + 1, -z; (vi) -x, y, -z.


Bis[hexa-amminecobalt(III)] penta-chloride nitrate.

Wu Q, Du C, Lv Y, Chen G, Pan Q - Acta Crystallogr Sect E Struct Rep Online (2012)

A view of the asymmetric unit of title compound showing the atom labelling scheme. Ellipsoids are drawn at the 30% probability level. [Symmetry codes: (i) -x, 1 - y, -z; (ii) -x, y, -z; (iii) x, 1 - y, z; (iv) 1 - x, 1 - y, -z; (v) 1 - x, y, -z; (vi) 1/2 - x, 1/2 - y, 1 - z]. (iv) x, -y + 1, z; (v) -x, -y + 1, -z; (vi) -x, y, -z.
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC3379055&req=5

Fap1: A view of the asymmetric unit of title compound showing the atom labelling scheme. Ellipsoids are drawn at the 30% probability level. [Symmetry codes: (i) -x, 1 - y, -z; (ii) -x, y, -z; (iii) x, 1 - y, z; (iv) 1 - x, 1 - y, -z; (v) 1 - x, y, -z; (vi) 1/2 - x, 1/2 - y, 1 - z]. (iv) x, -y + 1, z; (v) -x, -y + 1, -z; (vi) -x, y, -z.
Bottom Line: All Co(3+) ions are six-coordinated by NH(3) mol-ecules, forming [Co(NH(3))(6)](3+) octahedra, with Co-N distances in the range 1.945 (4)-1.967 (3) Å.The nitrate N atom and one of the O atoms lie at a mirror plane.Among the Cl(-) anions, one lies in a general position, one on a twofold axis and two on a mirror plane.

View Article: PubMed Central - HTML - PubMed

Affiliation: Department of Materials and Chemical Engineering, Ministry of Education Key Laboratory of Advanced Materials of Tropical Island Resources, Hainan University, Haikou 570228, People's Republic of China.

ABSTRACT
The title compound, [Co(NH(3))(6)](2)Cl(5)(NO(3)), was obtained under hydro-thermal conditions. The asymmetric unit contains three Co(3+) ions, one lying on an inversion center and the other two located at 2/m positions. All Co(3+) ions are six-coordinated by NH(3) mol-ecules, forming [Co(NH(3))(6)](3+) octahedra, with Co-N distances in the range 1.945 (4)-1.967 (3) Å. The nitrate N atom and one of the O atoms lie at a mirror plane. Among the Cl(-) anions, one lies in a general position, one on a twofold axis and two on a mirror plane. N-H⋯O and N-H⋯Cl hydrogen bonds link the cations and anions into a three-dimensional network.

No MeSH data available.


Related in: MedlinePlus