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N-(2,6-Diisopropyl-phen-yl)formamide toluene 0.33-solvate.

Berger M, Bats JW, Auner N - Acta Crystallogr Sect E Struct Rep Online (2012)

Bottom Line: The angle between the benzene ring and the mean plane of the formamide group is 71.1 (1)°.The amide groups of neighbouring mol-ecules are connected by N-H⋯O hydrogen bonds, forming 2(1) helical chains propagating along [001].Mol-ecules are also connected by weak inter-molecular C-H⋯O hydrogen bonds, forming 6(1) helices.

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ABSTRACT
The crystal packing of the title compound, C(13)H(19)NO·0.33C(7)H(8), shows a channel at [001], which contains grossly disordered toluene solvent mol-ecules. The angle between the benzene ring and the mean plane of the formamide group is 71.1 (1)°. The amide groups of neighbouring mol-ecules are connected by N-H⋯O hydrogen bonds, forming 2(1) helical chains propagating along [001]. Mol-ecules are also connected by weak inter-molecular C-H⋯O hydrogen bonds, forming 6(1) helices.

No MeSH data available.


The molecular structure of the title molecule, showing the atom-labelling. Displacement ellipsoids are drawn at the 50% probability level.
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Fap1: The molecular structure of the title molecule, showing the atom-labelling. Displacement ellipsoids are drawn at the 50% probability level.


N-(2,6-Diisopropyl-phen-yl)formamide toluene 0.33-solvate.

Berger M, Bats JW, Auner N - Acta Crystallogr Sect E Struct Rep Online (2012)

The molecular structure of the title molecule, showing the atom-labelling. Displacement ellipsoids are drawn at the 50% probability level.
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC3344661&req=5

Fap1: The molecular structure of the title molecule, showing the atom-labelling. Displacement ellipsoids are drawn at the 50% probability level.
Bottom Line: The angle between the benzene ring and the mean plane of the formamide group is 71.1 (1)°.The amide groups of neighbouring mol-ecules are connected by N-H⋯O hydrogen bonds, forming 2(1) helical chains propagating along [001].Mol-ecules are also connected by weak inter-molecular C-H⋯O hydrogen bonds, forming 6(1) helices.

View Article: PubMed Central - HTML - PubMed

ABSTRACT
The crystal packing of the title compound, C(13)H(19)NO·0.33C(7)H(8), shows a channel at [001], which contains grossly disordered toluene solvent mol-ecules. The angle between the benzene ring and the mean plane of the formamide group is 71.1 (1)°. The amide groups of neighbouring mol-ecules are connected by N-H⋯O hydrogen bonds, forming 2(1) helical chains propagating along [001]. Mol-ecules are also connected by weak inter-molecular C-H⋯O hydrogen bonds, forming 6(1) helices.

No MeSH data available.