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Guanidinium bromide-18-crown-6 (2/1).

Wang YF - Acta Crystallogr Sect E Struct Rep Online (2012)

Bottom Line: In the title compound, 2CH(6)N(3) (+)·2Br(-)·C(12)H(24)O(6), the 18-crown-6 mol-ecule lies about an inversion center, whereas the guanidinium cation and bromide anion are in general positions.The guanidinium cations link with the bromide anions and the crown ether mol-ecules via N-H⋯O and N-H⋯Br hydrogen bonds, thus forming a three-dimensional network.

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Affiliation: Ordered Matter Science Research Center, Southeast University, Nanjing 211189, People's Republic of China.

ABSTRACT
In the title compound, 2CH(6)N(3) (+)·2Br(-)·C(12)H(24)O(6), the 18-crown-6 mol-ecule lies about an inversion center, whereas the guanidinium cation and bromide anion are in general positions. The guanidinium cations link with the bromide anions and the crown ether mol-ecules via N-H⋯O and N-H⋯Br hydrogen bonds, thus forming a three-dimensional network.

No MeSH data available.


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A view of the packing of the title compound viewed along the a axis. Dashed lines indicate hydrogen bonds.
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Fap2: A view of the packing of the title compound viewed along the a axis. Dashed lines indicate hydrogen bonds.


Guanidinium bromide-18-crown-6 (2/1).

Wang YF - Acta Crystallogr Sect E Struct Rep Online (2012)

A view of the packing of the title compound viewed along the a axis. Dashed lines indicate hydrogen bonds.
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC3344632&req=5

Fap2: A view of the packing of the title compound viewed along the a axis. Dashed lines indicate hydrogen bonds.
Bottom Line: In the title compound, 2CH(6)N(3) (+)·2Br(-)·C(12)H(24)O(6), the 18-crown-6 mol-ecule lies about an inversion center, whereas the guanidinium cation and bromide anion are in general positions.The guanidinium cations link with the bromide anions and the crown ether mol-ecules via N-H⋯O and N-H⋯Br hydrogen bonds, thus forming a three-dimensional network.

View Article: PubMed Central - HTML - PubMed

Affiliation: Ordered Matter Science Research Center, Southeast University, Nanjing 211189, People's Republic of China.

ABSTRACT
In the title compound, 2CH(6)N(3) (+)·2Br(-)·C(12)H(24)O(6), the 18-crown-6 mol-ecule lies about an inversion center, whereas the guanidinium cation and bromide anion are in general positions. The guanidinium cations link with the bromide anions and the crown ether mol-ecules via N-H⋯O and N-H⋯Br hydrogen bonds, thus forming a three-dimensional network.

No MeSH data available.


Related in: MedlinePlus