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(2E)-2-[(2-Hy-droxy-4-meth-oxy-phen-yl)(phen-yl)methyl-idene]-N-phenyl-hydrazinecarboxamide dimethyl-formamide monosolvate.

Annie CF, Jacob JM, Sithambaresan M, Kurup MR - Acta Crystallogr Sect E Struct Rep Online (2012)

Bottom Line: The two N atoms of the hydrazinecarboxamide group are involved in inter-molecular N-H⋯O hydrogen bonds in which the dimethyl-formamide O atom acts as acceptor.The structure also features π-π inter-actions, with a centroid-centroid distance of 3.6561 (13) Å.Classical and non-classical intra-molecular O-H⋯N and C-H⋯O hydrogen bonds are also present.

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ABSTRACT
The title compound, C(21)H(19)N(3)O(3)·C(3)H(7)NO, adopts an E conformation with respect to the azomethine bond and crystallizes in the amide form. The dihedral angle between the rings lined to the C=N bond is 88.60 (12)°. The dimethyl-formamide solvent mol-ecule is disordered over two orientations with site occupancies of 0.684 (3) and 0.316 (3). The two N atoms of the hydrazinecarboxamide group are involved in inter-molecular N-H⋯O hydrogen bonds in which the dimethyl-formamide O atom acts as acceptor. The structure also features π-π inter-actions, with a centroid-centroid distance of 3.6561 (13) Å. Classical and non-classical intra-molecular O-H⋯N and C-H⋯O hydrogen bonds are also present.

No MeSH data available.


The molecular structure of the title compound, showing the disordered DMF solvent molecule.
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Fap1: The molecular structure of the title compound, showing the disordered DMF solvent molecule.


(2E)-2-[(2-Hy-droxy-4-meth-oxy-phen-yl)(phen-yl)methyl-idene]-N-phenyl-hydrazinecarboxamide dimethyl-formamide monosolvate.

Annie CF, Jacob JM, Sithambaresan M, Kurup MR - Acta Crystallogr Sect E Struct Rep Online (2012)

The molecular structure of the title compound, showing the disordered DMF solvent molecule.
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC3344624&req=5

Fap1: The molecular structure of the title compound, showing the disordered DMF solvent molecule.
Bottom Line: The two N atoms of the hydrazinecarboxamide group are involved in inter-molecular N-H⋯O hydrogen bonds in which the dimethyl-formamide O atom acts as acceptor.The structure also features π-π inter-actions, with a centroid-centroid distance of 3.6561 (13) Å.Classical and non-classical intra-molecular O-H⋯N and C-H⋯O hydrogen bonds are also present.

View Article: PubMed Central - HTML - PubMed

ABSTRACT
The title compound, C(21)H(19)N(3)O(3)·C(3)H(7)NO, adopts an E conformation with respect to the azomethine bond and crystallizes in the amide form. The dihedral angle between the rings lined to the C=N bond is 88.60 (12)°. The dimethyl-formamide solvent mol-ecule is disordered over two orientations with site occupancies of 0.684 (3) and 0.316 (3). The two N atoms of the hydrazinecarboxamide group are involved in inter-molecular N-H⋯O hydrogen bonds in which the dimethyl-formamide O atom acts as acceptor. The structure also features π-π inter-actions, with a centroid-centroid distance of 3.6561 (13) Å. Classical and non-classical intra-molecular O-H⋯N and C-H⋯O hydrogen bonds are also present.

No MeSH data available.