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2-Eth-oxy-6-[1-(3-eth-oxy-2-hy-droxy-benz-yl)-2,3-dihydro-1H-benzimidazol-2-yl]phenol acetonitrile monosolvate.

Ha K - Acta Crystallogr Sect E Struct Rep Online (2012)

Bottom Line: The dihedral angle between the benzene rings is 80.36 (9)°.In the mol-ecule, there are strong O-H⋯N and O-H⋯O hydrogen bonds.In the crystal, mol-ecules are connected by bifurcated O-H⋯(O,O) hydrogen bonds, forming chains propagating along [010].

View Article: PubMed Central - HTML - PubMed

Affiliation: School of Applied Chemical Engineering, The Research Institute of Catalysis, Chonnam National University, Gwangju 500-757, Republic of Korea.

ABSTRACT
The title compound, C(24)H(24)N(2)O(4)·CH(3)CN, a disubstituted benzimidazole, crystallized as an acetonitrile monosolvate. The benzene ring of the 2-eth-oxy-6-methyl-phenol substiuent is approximately perpendicular to the nearly planar benzimidazole ring system [maximum deviation = 0.016 (1) Å], making a dihedral angle of 84.27 (8)°. The benzene ring of the 2-eth-oxy-phenol substituent is inclined to the benzimidazole mean plane by 29.68 (8)°. The dihedral angle between the benzene rings is 80.36 (9)°. In the mol-ecule, there are strong O-H⋯N and O-H⋯O hydrogen bonds. In the crystal, mol-ecules are connected by bifurcated O-H⋯(O,O) hydrogen bonds, forming chains propagating along [010].

No MeSH data available.


The molecular structure of the title compound, with atom numbering. Displacement ellipsoids are drawn at the 40% probability level. Intramolecular hydrogen-bonds are shown as dashed lines (see Table 1 for details).
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Fap1: The molecular structure of the title compound, with atom numbering. Displacement ellipsoids are drawn at the 40% probability level. Intramolecular hydrogen-bonds are shown as dashed lines (see Table 1 for details).


2-Eth-oxy-6-[1-(3-eth-oxy-2-hy-droxy-benz-yl)-2,3-dihydro-1H-benzimidazol-2-yl]phenol acetonitrile monosolvate.

Ha K - Acta Crystallogr Sect E Struct Rep Online (2012)

The molecular structure of the title compound, with atom numbering. Displacement ellipsoids are drawn at the 40% probability level. Intramolecular hydrogen-bonds are shown as dashed lines (see Table 1 for details).
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC3344524&req=5

Fap1: The molecular structure of the title compound, with atom numbering. Displacement ellipsoids are drawn at the 40% probability level. Intramolecular hydrogen-bonds are shown as dashed lines (see Table 1 for details).
Bottom Line: The dihedral angle between the benzene rings is 80.36 (9)°.In the mol-ecule, there are strong O-H⋯N and O-H⋯O hydrogen bonds.In the crystal, mol-ecules are connected by bifurcated O-H⋯(O,O) hydrogen bonds, forming chains propagating along [010].

View Article: PubMed Central - HTML - PubMed

Affiliation: School of Applied Chemical Engineering, The Research Institute of Catalysis, Chonnam National University, Gwangju 500-757, Republic of Korea.

ABSTRACT
The title compound, C(24)H(24)N(2)O(4)·CH(3)CN, a disubstituted benzimidazole, crystallized as an acetonitrile monosolvate. The benzene ring of the 2-eth-oxy-6-methyl-phenol substiuent is approximately perpendicular to the nearly planar benzimidazole ring system [maximum deviation = 0.016 (1) Å], making a dihedral angle of 84.27 (8)°. The benzene ring of the 2-eth-oxy-phenol substituent is inclined to the benzimidazole mean plane by 29.68 (8)°. The dihedral angle between the benzene rings is 80.36 (9)°. In the mol-ecule, there are strong O-H⋯N and O-H⋯O hydrogen bonds. In the crystal, mol-ecules are connected by bifurcated O-H⋯(O,O) hydrogen bonds, forming chains propagating along [010].

No MeSH data available.