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1,1,2,2-Tetra-kis(dimethyl-amino)-ethane-1,2-diium bis-(tetra-phenyl-borate) acetone disolvate.

Tiritiris I, Kantlehner W - Acta Crystallogr Sect E Struct Rep Online (2012)

Bottom Line: The title compound, C(10)H(24)N(4) (2+)·2C(24)H(20)B(-)·2C(3)H(6)O, crystallizes with two acetone solvent mol-ecules per asymmetric unit.In the dication, both amidinium units are twisted about the central C-C single bond by 63.8 (3)° and the positive charges are delocalized over both N-C-N planes.

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ABSTRACT
The title compound, C(10)H(24)N(4) (2+)·2C(24)H(20)B(-)·2C(3)H(6)O, crystallizes with two acetone solvent mol-ecules per asymmetric unit. In the dication, both amidinium units are twisted about the central C-C single bond by 63.8 (3)° and the positive charges are delocalized over both N-C-N planes.

No MeSH data available.


Molecular structure of the title compound showing 50% probability displacement ellipsoids. All H atoms were omitted for clarity.
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Fap1: Molecular structure of the title compound showing 50% probability displacement ellipsoids. All H atoms were omitted for clarity.


1,1,2,2-Tetra-kis(dimethyl-amino)-ethane-1,2-diium bis-(tetra-phenyl-borate) acetone disolvate.

Tiritiris I, Kantlehner W - Acta Crystallogr Sect E Struct Rep Online (2012)

Molecular structure of the title compound showing 50% probability displacement ellipsoids. All H atoms were omitted for clarity.
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC3344502&req=5

Fap1: Molecular structure of the title compound showing 50% probability displacement ellipsoids. All H atoms were omitted for clarity.
Bottom Line: The title compound, C(10)H(24)N(4) (2+)·2C(24)H(20)B(-)·2C(3)H(6)O, crystallizes with two acetone solvent mol-ecules per asymmetric unit.In the dication, both amidinium units are twisted about the central C-C single bond by 63.8 (3)° and the positive charges are delocalized over both N-C-N planes.

View Article: PubMed Central - HTML - PubMed

ABSTRACT
The title compound, C(10)H(24)N(4) (2+)·2C(24)H(20)B(-)·2C(3)H(6)O, crystallizes with two acetone solvent mol-ecules per asymmetric unit. In the dication, both amidinium units are twisted about the central C-C single bond by 63.8 (3)° and the positive charges are delocalized over both N-C-N planes.

No MeSH data available.