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(E)-Methyl 2-benzyl-3-o-tolyl-acrylate.

Karthikeyan S, Sethusankar K, Devaraj A, Bakthadoss M - Acta Crystallogr Sect E Struct Rep Online (2012)

Bottom Line: The mean plane of the acrylate unit and the phenyl ring are approximately orthogonal to each other, making a dihedral angle of 81.40 (6)°.The position of the carbonyl group with respect to the olefinic double bond is typically S-trans.The crystal packing is stabilized by inter-molecular C-H⋯π inter-actions.

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ABSTRACT
In the title compound, C(18)H(18)O(2), the methyl acrylate substituent adopts an extended E conformation with all torsion angles close to 180°. The mean plane of the acrylate unit and the phenyl ring are approximately orthogonal to each other, making a dihedral angle of 81.40 (6)°. The position of the carbonyl group with respect to the olefinic double bond is typically S-trans. The crystal packing is stabilized by inter-molecular C-H⋯π inter-actions.

No MeSH data available.


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The packing arrangement of the title compound viewed down c axis. The dashed line indicate C3–H3···Cg1i intermolecular interaction. Cg1 is the centroid of the benzene ring (C13-C18). Symmetry code: (i) x+1, -y-1/2, z-3/2.
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Fap2: The packing arrangement of the title compound viewed down c axis. The dashed line indicate C3–H3···Cg1i intermolecular interaction. Cg1 is the centroid of the benzene ring (C13-C18). Symmetry code: (i) x+1, -y-1/2, z-3/2.


(E)-Methyl 2-benzyl-3-o-tolyl-acrylate.

Karthikeyan S, Sethusankar K, Devaraj A, Bakthadoss M - Acta Crystallogr Sect E Struct Rep Online (2012)

The packing arrangement of the title compound viewed down c axis. The dashed line indicate C3–H3···Cg1i intermolecular interaction. Cg1 is the centroid of the benzene ring (C13-C18). Symmetry code: (i) x+1, -y-1/2, z-3/2.
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC3344426&req=5

Fap2: The packing arrangement of the title compound viewed down c axis. The dashed line indicate C3–H3···Cg1i intermolecular interaction. Cg1 is the centroid of the benzene ring (C13-C18). Symmetry code: (i) x+1, -y-1/2, z-3/2.
Bottom Line: The mean plane of the acrylate unit and the phenyl ring are approximately orthogonal to each other, making a dihedral angle of 81.40 (6)°.The position of the carbonyl group with respect to the olefinic double bond is typically S-trans.The crystal packing is stabilized by inter-molecular C-H⋯π inter-actions.

View Article: PubMed Central - HTML - PubMed

ABSTRACT
In the title compound, C(18)H(18)O(2), the methyl acrylate substituent adopts an extended E conformation with all torsion angles close to 180°. The mean plane of the acrylate unit and the phenyl ring are approximately orthogonal to each other, making a dihedral angle of 81.40 (6)°. The position of the carbonyl group with respect to the olefinic double bond is typically S-trans. The crystal packing is stabilized by inter-molecular C-H⋯π inter-actions.

No MeSH data available.


Related in: MedlinePlus