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Poly[di-μ(3)-acetato-μ(8)-(naphthalene-1,5-disulfonato)-dilead(II)].

Gao S, Ng SW - Acta Crystallogr Sect E Struct Rep Online (2012)

Bottom Line: In the polymeric title complex, [Pb(2)(CH(3)CO(2))(2)(C(10)H(6)O(6)S(2))](n), the acetate anion functions in a chelating mode and both O atoms also coordinate to adjacent Pb(II) atoms.The bridging modes of the monoanion and dianion give rise to a three-dimensional coordination polymer.The Pb(II) atom is eight-coordinate in the form of an undefined coordination polyhedron.

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ABSTRACT
In the polymeric title complex, [Pb(2)(CH(3)CO(2))(2)(C(10)H(6)O(6)S(2))](n), the acetate anion functions in a chelating mode and both O atoms also coordinate to adjacent Pb(II) atoms. The naphthalene-1,5-disulfonate dianion, which lies on a center of inversion, is connected to four Pb(II) atoms. The bridging modes of the monoanion and dianion give rise to a three-dimensional coordination polymer. The Pb(II) atom is eight-coordinate in the form of an undefined coordination polyhedron.

No MeSH data available.


Related in: MedlinePlus

Eight-coordinate geometry of PbII.
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Fap2: Eight-coordinate geometry of PbII.


Poly[di-μ(3)-acetato-μ(8)-(naphthalene-1,5-disulfonato)-dilead(II)].

Gao S, Ng SW - Acta Crystallogr Sect E Struct Rep Online (2012)

Eight-coordinate geometry of PbII.
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC3344422&req=5

Fap2: Eight-coordinate geometry of PbII.
Bottom Line: In the polymeric title complex, [Pb(2)(CH(3)CO(2))(2)(C(10)H(6)O(6)S(2))](n), the acetate anion functions in a chelating mode and both O atoms also coordinate to adjacent Pb(II) atoms.The bridging modes of the monoanion and dianion give rise to a three-dimensional coordination polymer.The Pb(II) atom is eight-coordinate in the form of an undefined coordination polyhedron.

View Article: PubMed Central - HTML - PubMed

ABSTRACT
In the polymeric title complex, [Pb(2)(CH(3)CO(2))(2)(C(10)H(6)O(6)S(2))](n), the acetate anion functions in a chelating mode and both O atoms also coordinate to adjacent Pb(II) atoms. The naphthalene-1,5-disulfonate dianion, which lies on a center of inversion, is connected to four Pb(II) atoms. The bridging modes of the monoanion and dianion give rise to a three-dimensional coordination polymer. The Pb(II) atom is eight-coordinate in the form of an undefined coordination polyhedron.

No MeSH data available.


Related in: MedlinePlus