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Tetra-kis(triphenyl-phosphane-κP)silver(I) tetra-fluorido-borate.

Huang X, Qiu QM, Wang X, Jin QH, Zhang CL - Acta Crystallogr Sect E Struct Rep Online (2012)

Bottom Line: The Ag(I) atom is tetra-hedrally coordinated by four P atoms from triphenyl-phosphane (PPh(3)) ligands.Due to symmetry, the tetra-fluorido-borate anion is disordered over three positions (each with one third occupancy).The tetra-fluorido-borate anion does not coordinate to the Ag(I) atom.

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ABSTRACT
The title complex, [Ag(C(18)H(15)P)(4)]BF(4), was prepared by the reaction of silver(I) tetra-fluorido-borate and triphenyl-phosphane in the presence of 1,2-bis-(pyridin-2-yl)ethyl-ene. The Ag(I) atom is tetra-hedrally coordinated by four P atoms from triphenyl-phosphane (PPh(3)) ligands. Due to symmetry, the tetra-fluorido-borate anion is disordered over three positions (each with one third occupancy). The tetra-fluorido-borate anion does not coordinate to the Ag(I) atom.

No MeSH data available.


The molecular entities of the title compound, showing the atom-numbering scheme and with displacement ellipsoids drawn at the 50% probability level.
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Fap1: The molecular entities of the title compound, showing the atom-numbering scheme and with displacement ellipsoids drawn at the 50% probability level.


Tetra-kis(triphenyl-phosphane-κP)silver(I) tetra-fluorido-borate.

Huang X, Qiu QM, Wang X, Jin QH, Zhang CL - Acta Crystallogr Sect E Struct Rep Online (2012)

The molecular entities of the title compound, showing the atom-numbering scheme and with displacement ellipsoids drawn at the 50% probability level.
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC3344421&req=5

Fap1: The molecular entities of the title compound, showing the atom-numbering scheme and with displacement ellipsoids drawn at the 50% probability level.
Bottom Line: The Ag(I) atom is tetra-hedrally coordinated by four P atoms from triphenyl-phosphane (PPh(3)) ligands.Due to symmetry, the tetra-fluorido-borate anion is disordered over three positions (each with one third occupancy).The tetra-fluorido-borate anion does not coordinate to the Ag(I) atom.

View Article: PubMed Central - HTML - PubMed

ABSTRACT
The title complex, [Ag(C(18)H(15)P)(4)]BF(4), was prepared by the reaction of silver(I) tetra-fluorido-borate and triphenyl-phosphane in the presence of 1,2-bis-(pyridin-2-yl)ethyl-ene. The Ag(I) atom is tetra-hedrally coordinated by four P atoms from triphenyl-phosphane (PPh(3)) ligands. Due to symmetry, the tetra-fluorido-borate anion is disordered over three positions (each with one third occupancy). The tetra-fluorido-borate anion does not coordinate to the Ag(I) atom.

No MeSH data available.