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Poly[[μ-ethane-1,2-diyl bis-(pyridine-3-carboxyl-ate)](μ-tetra-fluorido-borato)silver(I)].

Vallejos J, Brito I, Cárdenas A, Bolte M - Acta Crystallogr Sect E Struct Rep Online (2012)

Bottom Line: In the title compound, [Ag(BF(4))(C(14)H(12)N(2)O(4))](n), the coordination of the Ag(+) ion is trigonal-bipyramidal with the N atoms of two ethane-1,2-diyl bis-(pyridine-3-carboxyl-ate) ligands in the apical positions and three F atoms belonging to different tetra-fluorido-borate anions in the equatorial plane.The material consists of infinite chains of [Ag(C(14)H(12)N(2)O(4))] units running along [001], held together by BF(4) (-) bridging anions.

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ABSTRACT
In the title compound, [Ag(BF(4))(C(14)H(12)N(2)O(4))](n), the coordination of the Ag(+) ion is trigonal-bipyramidal with the N atoms of two ethane-1,2-diyl bis-(pyridine-3-carboxyl-ate) ligands in the apical positions and three F atoms belonging to different tetra-fluorido-borate anions in the equatorial plane. The material consists of infinite chains of [Ag(C(14)H(12)N(2)O(4))] units running along [001], held together by BF(4) (-) bridging anions.

No MeSH data available.


Part of the polymeric structure and the atom-numbering scheme of the title compound. Displacement ellipsoids are shown at the 30% probability level. [Symmetry codes (i) x, 3/2 - y, -1/2 + z; (ii) 1/2 - x, 1/2 + y, z; (iii) 1/2 - x, -1/2 + y, z].
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Fap1: Part of the polymeric structure and the atom-numbering scheme of the title compound. Displacement ellipsoids are shown at the 30% probability level. [Symmetry codes (i) x, 3/2 - y, -1/2 + z; (ii) 1/2 - x, 1/2 + y, z; (iii) 1/2 - x, -1/2 + y, z].


Poly[[μ-ethane-1,2-diyl bis-(pyridine-3-carboxyl-ate)](μ-tetra-fluorido-borato)silver(I)].

Vallejos J, Brito I, Cárdenas A, Bolte M - Acta Crystallogr Sect E Struct Rep Online (2012)

Part of the polymeric structure and the atom-numbering scheme of the title compound. Displacement ellipsoids are shown at the 30% probability level. [Symmetry codes (i) x, 3/2 - y, -1/2 + z; (ii) 1/2 - x, 1/2 + y, z; (iii) 1/2 - x, -1/2 + y, z].
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC3344420&req=5

Fap1: Part of the polymeric structure and the atom-numbering scheme of the title compound. Displacement ellipsoids are shown at the 30% probability level. [Symmetry codes (i) x, 3/2 - y, -1/2 + z; (ii) 1/2 - x, 1/2 + y, z; (iii) 1/2 - x, -1/2 + y, z].
Bottom Line: In the title compound, [Ag(BF(4))(C(14)H(12)N(2)O(4))](n), the coordination of the Ag(+) ion is trigonal-bipyramidal with the N atoms of two ethane-1,2-diyl bis-(pyridine-3-carboxyl-ate) ligands in the apical positions and three F atoms belonging to different tetra-fluorido-borate anions in the equatorial plane.The material consists of infinite chains of [Ag(C(14)H(12)N(2)O(4))] units running along [001], held together by BF(4) (-) bridging anions.

View Article: PubMed Central - HTML - PubMed

ABSTRACT
In the title compound, [Ag(BF(4))(C(14)H(12)N(2)O(4))](n), the coordination of the Ag(+) ion is trigonal-bipyramidal with the N atoms of two ethane-1,2-diyl bis-(pyridine-3-carboxyl-ate) ligands in the apical positions and three F atoms belonging to different tetra-fluorido-borate anions in the equatorial plane. The material consists of infinite chains of [Ag(C(14)H(12)N(2)O(4))] units running along [001], held together by BF(4) (-) bridging anions.

No MeSH data available.