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catena-Poly[[bis-(3-acetyl-pyridine-κN)cadmium]-di-μ-seleno-cyanato-κ(2)N:Se;κ(2)Se:N].

Werner J, Boeckmann J, Jess I, Näther C - Acta Crystallogr Sect E Struct Rep Online (2012)

Bottom Line: In the crystal structure of the title compound, [Cd(NCSe)(2)(C(7)H(7)NO)(2)](n), the Cd(2+) cation is coordinated by two 3-acetyl-pyridine ligands and four μ-1,3-bridging seleno-cyanate anions within a slightly distorted CdN(4)Se(2) octa-hedron.The asymmetric units consists of one Cd(2+) cation, which is situated on a center of inversion, as well as one seleno-cyanate anion and one 3-acetyl-pyridine ligand in general positions.The metal cations are μ-1,3-bridged via the seleno-cyanate anions into chains along the a axis.

View Article: PubMed Central - HTML - PubMed

Affiliation: Institut für Anorganische Chemie, Christian-Albrechts-Universität Kiel, Max-Eyth-Strasse 2, 24118 Kiel, Germany.

ABSTRACT
In the crystal structure of the title compound, [Cd(NCSe)(2)(C(7)H(7)NO)(2)](n), the Cd(2+) cation is coordinated by two 3-acetyl-pyridine ligands and four μ-1,3-bridging seleno-cyanate anions within a slightly distorted CdN(4)Se(2) octa-hedron. The asymmetric units consists of one Cd(2+) cation, which is situated on a center of inversion, as well as one seleno-cyanate anion and one 3-acetyl-pyridine ligand in general positions. The metal cations are μ-1,3-bridged via the seleno-cyanate anions into chains along the a axis.

No MeSH data available.


Related in: MedlinePlus

: Crystal structure of the title compound with view of the chains that elongate in the direction of the crystallographic a axis.
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Fap2: : Crystal structure of the title compound with view of the chains that elongate in the direction of the crystallographic a axis.


catena-Poly[[bis-(3-acetyl-pyridine-κN)cadmium]-di-μ-seleno-cyanato-κ(2)N:Se;κ(2)Se:N].

Werner J, Boeckmann J, Jess I, Näther C - Acta Crystallogr Sect E Struct Rep Online (2012)

: Crystal structure of the title compound with view of the chains that elongate in the direction of the crystallographic a axis.
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC3344419&req=5

Fap2: : Crystal structure of the title compound with view of the chains that elongate in the direction of the crystallographic a axis.
Bottom Line: In the crystal structure of the title compound, [Cd(NCSe)(2)(C(7)H(7)NO)(2)](n), the Cd(2+) cation is coordinated by two 3-acetyl-pyridine ligands and four μ-1,3-bridging seleno-cyanate anions within a slightly distorted CdN(4)Se(2) octa-hedron.The asymmetric units consists of one Cd(2+) cation, which is situated on a center of inversion, as well as one seleno-cyanate anion and one 3-acetyl-pyridine ligand in general positions.The metal cations are μ-1,3-bridged via the seleno-cyanate anions into chains along the a axis.

View Article: PubMed Central - HTML - PubMed

Affiliation: Institut für Anorganische Chemie, Christian-Albrechts-Universität Kiel, Max-Eyth-Strasse 2, 24118 Kiel, Germany.

ABSTRACT
In the crystal structure of the title compound, [Cd(NCSe)(2)(C(7)H(7)NO)(2)](n), the Cd(2+) cation is coordinated by two 3-acetyl-pyridine ligands and four μ-1,3-bridging seleno-cyanate anions within a slightly distorted CdN(4)Se(2) octa-hedron. The asymmetric units consists of one Cd(2+) cation, which is situated on a center of inversion, as well as one seleno-cyanate anion and one 3-acetyl-pyridine ligand in general positions. The metal cations are μ-1,3-bridged via the seleno-cyanate anions into chains along the a axis.

No MeSH data available.


Related in: MedlinePlus