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Hexa-kis-(dimethyl sulfoxide-κO)calcium μ(6)-oxido-dodeca-kis-μ(2)-oxido-hexa-oxido-hexa-tungstate(VI).

Zhang J - Acta Crystallogr Sect E Struct Rep Online (2012)

Bottom Line: In the title compound, [Ca(C(2)H(6)OS)(6)][W(6)O(19)], the cation and anion both have a crystallographically imposed centre of symmetry.The Ca(II) atom in the cation is coordinated by six O atoms from six dimethyl sulfoxide ligands in a distorted octa-hedral geometry.The [W(6)O(19)](2-) isopolyanion possesses the well-known Lindqvist structure in which each W(VI) atom is coordinated by four μ(2)-O, one terminal O and one μ(6)-O atom.

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Affiliation: Molecular Materials Research Center, Scientific Research Academy, School of Chemistry and Chemical Engineering, Jiangsu University, Zhenjiang 212013, People's Republic of China.

ABSTRACT
In the title compound, [Ca(C(2)H(6)OS)(6)][W(6)O(19)], the cation and anion both have a crystallographically imposed centre of symmetry. The Ca(II) atom in the cation is coordinated by six O atoms from six dimethyl sulfoxide ligands in a distorted octa-hedral geometry. The [W(6)O(19)](2-) isopolyanion possesses the well-known Lindqvist structure in which each W(VI) atom is coordinated by four μ(2)-O, one terminal O and one μ(6)-O atom.

No MeSH data available.


The molecular structure of the anion in the title compound, with 30% probability displacement ellipsoids. Symmetry code: (i) 1 - x, -y, -z.
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Fap2: The molecular structure of the anion in the title compound, with 30% probability displacement ellipsoids. Symmetry code: (i) 1 - x, -y, -z.


Hexa-kis-(dimethyl sulfoxide-κO)calcium μ(6)-oxido-dodeca-kis-μ(2)-oxido-hexa-oxido-hexa-tungstate(VI).

Zhang J - Acta Crystallogr Sect E Struct Rep Online (2012)

The molecular structure of the anion in the title compound, with 30% probability displacement ellipsoids. Symmetry code: (i) 1 - x, -y, -z.
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC3344417&req=5

Fap2: The molecular structure of the anion in the title compound, with 30% probability displacement ellipsoids. Symmetry code: (i) 1 - x, -y, -z.
Bottom Line: In the title compound, [Ca(C(2)H(6)OS)(6)][W(6)O(19)], the cation and anion both have a crystallographically imposed centre of symmetry.The Ca(II) atom in the cation is coordinated by six O atoms from six dimethyl sulfoxide ligands in a distorted octa-hedral geometry.The [W(6)O(19)](2-) isopolyanion possesses the well-known Lindqvist structure in which each W(VI) atom is coordinated by four μ(2)-O, one terminal O and one μ(6)-O atom.

View Article: PubMed Central - HTML - PubMed

Affiliation: Molecular Materials Research Center, Scientific Research Academy, School of Chemistry and Chemical Engineering, Jiangsu University, Zhenjiang 212013, People's Republic of China.

ABSTRACT
In the title compound, [Ca(C(2)H(6)OS)(6)][W(6)O(19)], the cation and anion both have a crystallographically imposed centre of symmetry. The Ca(II) atom in the cation is coordinated by six O atoms from six dimethyl sulfoxide ligands in a distorted octa-hedral geometry. The [W(6)O(19)](2-) isopolyanion possesses the well-known Lindqvist structure in which each W(VI) atom is coordinated by four μ(2)-O, one terminal O and one μ(6)-O atom.

No MeSH data available.