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Tris(1,10-phenanthrolin-1-ium) hexa-cyanidoferrate(III) ethanol monosolvate trihydrate.

Liu XQ, Yu DY, Yuan AH - Acta Crystallogr Sect E Struct Rep Online (2012)

Bottom Line: The asymmetric unit of the title complex, (C(12)H(9)N(2))(3)[Fe(CN)(6)]·C(2)H(5)OH·3H(2)O, consists of two half [Fe(CN)(6)](3-) anions located on inversion centers, three 1,10-phenanthrolin-1-ium cations, [Hphen](+), an ethanol and three water solvent mol-ecules.The Fe(III) atoms adopt a distorted octa-hedral geometry.All the species are linked through O-H⋯N, N-H⋯O and O-H⋯O hydrogen-bonding inter-actions, resulting in a three-dimensional supra-molecular network.

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ABSTRACT
The asymmetric unit of the title complex, (C(12)H(9)N(2))(3)[Fe(CN)(6)]·C(2)H(5)OH·3H(2)O, consists of two half [Fe(CN)(6)](3-) anions located on inversion centers, three 1,10-phenanthrolin-1-ium cations, [Hphen](+), an ethanol and three water solvent mol-ecules. The average Fe-C and C-N bond lengths are 1.942 (6) and 1.154 (3) Å, respectively, while the Fe-C-N angles deviate slightly from linearity with values ranging from 177.8 (2) to 179.7 (2)°. The Fe(III) atoms adopt a distorted octa-hedral geometry. All the species are linked through O-H⋯N, N-H⋯O and O-H⋯O hydrogen-bonding inter-actions, resulting in a three-dimensional supra-molecular network.

No MeSH data available.


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A three-dimensional supramolecular network of the title complex. Dotted lines represent hydrogen-bonding interactions.
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Fap2: A three-dimensional supramolecular network of the title complex. Dotted lines represent hydrogen-bonding interactions.


Tris(1,10-phenanthrolin-1-ium) hexa-cyanidoferrate(III) ethanol monosolvate trihydrate.

Liu XQ, Yu DY, Yuan AH - Acta Crystallogr Sect E Struct Rep Online (2012)

A three-dimensional supramolecular network of the title complex. Dotted lines represent hydrogen-bonding interactions.
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC3344416&req=5

Fap2: A three-dimensional supramolecular network of the title complex. Dotted lines represent hydrogen-bonding interactions.
Bottom Line: The asymmetric unit of the title complex, (C(12)H(9)N(2))(3)[Fe(CN)(6)]·C(2)H(5)OH·3H(2)O, consists of two half [Fe(CN)(6)](3-) anions located on inversion centers, three 1,10-phenanthrolin-1-ium cations, [Hphen](+), an ethanol and three water solvent mol-ecules.The Fe(III) atoms adopt a distorted octa-hedral geometry.All the species are linked through O-H⋯N, N-H⋯O and O-H⋯O hydrogen-bonding inter-actions, resulting in a three-dimensional supra-molecular network.

View Article: PubMed Central - HTML - PubMed

ABSTRACT
The asymmetric unit of the title complex, (C(12)H(9)N(2))(3)[Fe(CN)(6)]·C(2)H(5)OH·3H(2)O, consists of two half [Fe(CN)(6)](3-) anions located on inversion centers, three 1,10-phenanthrolin-1-ium cations, [Hphen](+), an ethanol and three water solvent mol-ecules. The average Fe-C and C-N bond lengths are 1.942 (6) and 1.154 (3) Å, respectively, while the Fe-C-N angles deviate slightly from linearity with values ranging from 177.8 (2) to 179.7 (2)°. The Fe(III) atoms adopt a distorted octa-hedral geometry. All the species are linked through O-H⋯N, N-H⋯O and O-H⋯O hydrogen-bonding inter-actions, resulting in a three-dimensional supra-molecular network.

No MeSH data available.


Related in: MedlinePlus