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catena-Poly[[(2,2'-bipyidine-2κ(2)N,N')-μ-cyanido-1:2κ(2)N:C-dicopper(I)]-μ-bromido-[(2,2'-bipyidine-2κ(2)N,N')-μ-cyanido-1:2κ(2)N:C-dicopper(I)]-μ-cyanido-κ(2)N:C].

Gu J, Jiang X, Su Z, Zhou B - Acta Crystallogr Sect E Struct Rep Online (2012)

Bottom Line: In the title complex, [Cu(4)Br(CN)(3)(C(10)H(8)N(2))(2)](n), the four independent Cu(I) atoms are all in distorted trigonal-planar geometries.One is formed by one N atom and one C atom from two cyanide groups and one Br atom, one is formed by two N atoms from two cyanide groups and one Br atom, and the other two are formed by two N atoms from a chelating 2,2'-bipyridine (bpy) ligand and one C atom from a cyanide group.The structure exhibits a zigzag chain backbone along [101] constructed by bromide and cyanide anions bridging the Cu(I) atoms, with the [Cu(bpy)(CN)] units pointing laterally.

View Article: PubMed Central - HTML - PubMed

Affiliation: Colleges of Chemistry & Chemical Engineering, Harbin Normal University, Harbin 150025, People's Republic of China.

ABSTRACT
In the title complex, [Cu(4)Br(CN)(3)(C(10)H(8)N(2))(2)](n), the four independent Cu(I) atoms are all in distorted trigonal-planar geometries. One is formed by one N atom and one C atom from two cyanide groups and one Br atom, one is formed by two N atoms from two cyanide groups and one Br atom, and the other two are formed by two N atoms from a chelating 2,2'-bipyridine (bpy) ligand and one C atom from a cyanide group. The structure exhibits a zigzag chain backbone along [101] constructed by bromide and cyanide anions bridging the Cu(I) atoms, with the [Cu(bpy)(CN)] units pointing laterally.

No MeSH data available.


The asymmetric unit of the title complex, showing the coordination environments around the CuI atoms. Displacement ellipsoids are drawn at 50% probability level. [Symmetry code: (i) x+1/2, -y+1/2, z+1/2.]
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Fap1: The asymmetric unit of the title complex, showing the coordination environments around the CuI atoms. Displacement ellipsoids are drawn at 50% probability level. [Symmetry code: (i) x+1/2, -y+1/2, z+1/2.]


catena-Poly[[(2,2'-bipyidine-2κ(2)N,N')-μ-cyanido-1:2κ(2)N:C-dicopper(I)]-μ-bromido-[(2,2'-bipyidine-2κ(2)N,N')-μ-cyanido-1:2κ(2)N:C-dicopper(I)]-μ-cyanido-κ(2)N:C].

Gu J, Jiang X, Su Z, Zhou B - Acta Crystallogr Sect E Struct Rep Online (2012)

The asymmetric unit of the title complex, showing the coordination environments around the CuI atoms. Displacement ellipsoids are drawn at 50% probability level. [Symmetry code: (i) x+1/2, -y+1/2, z+1/2.]
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC3344411&req=5

Fap1: The asymmetric unit of the title complex, showing the coordination environments around the CuI atoms. Displacement ellipsoids are drawn at 50% probability level. [Symmetry code: (i) x+1/2, -y+1/2, z+1/2.]
Bottom Line: In the title complex, [Cu(4)Br(CN)(3)(C(10)H(8)N(2))(2)](n), the four independent Cu(I) atoms are all in distorted trigonal-planar geometries.One is formed by one N atom and one C atom from two cyanide groups and one Br atom, one is formed by two N atoms from two cyanide groups and one Br atom, and the other two are formed by two N atoms from a chelating 2,2'-bipyridine (bpy) ligand and one C atom from a cyanide group.The structure exhibits a zigzag chain backbone along [101] constructed by bromide and cyanide anions bridging the Cu(I) atoms, with the [Cu(bpy)(CN)] units pointing laterally.

View Article: PubMed Central - HTML - PubMed

Affiliation: Colleges of Chemistry & Chemical Engineering, Harbin Normal University, Harbin 150025, People's Republic of China.

ABSTRACT
In the title complex, [Cu(4)Br(CN)(3)(C(10)H(8)N(2))(2)](n), the four independent Cu(I) atoms are all in distorted trigonal-planar geometries. One is formed by one N atom and one C atom from two cyanide groups and one Br atom, one is formed by two N atoms from two cyanide groups and one Br atom, and the other two are formed by two N atoms from a chelating 2,2'-bipyridine (bpy) ligand and one C atom from a cyanide group. The structure exhibits a zigzag chain backbone along [101] constructed by bromide and cyanide anions bridging the Cu(I) atoms, with the [Cu(bpy)(CN)] units pointing laterally.

No MeSH data available.