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Di-μ-bromido-bis-{[N,N-dimethyl-N'-(thio-phen-2-yl-methyl-idene)ethane-1,2-diamine]-copper(I)]}.

Goh C, Remillard ZD, Martinez AP, Keeley AC, Jasinski JP - Acta Crystallogr Sect E Struct Rep Online (2012)

Bottom Line: In the crystal structure of the title compound, [Cu(2)Br(2)(C(9)H(14)N(2)S)(2)], the mol-ecule resides about a crystallographic inversion center.The thio-phene ring is disordered over two sites, with occupancies of 0.719 (3) and 0.281 (3).Weak C-H⋯π inter-actions feature in the crystal packing.

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ABSTRACT
In the crystal structure of the title compound, [Cu(2)Br(2)(C(9)H(14)N(2)S)(2)], the mol-ecule resides about a crystallographic inversion center. The coordination sphere around each copper ion has a distorted tetra-hedral geometry, with ligation by two bridging bromide ions, an amine N atom and an imine N atom. The thio-phene ring is disordered over two sites, with occupancies of 0.719 (3) and 0.281 (3). Weak C-H⋯π inter-actions feature in the crystal packing.

No MeSH data available.


Related in: MedlinePlus

Molecular structure of the title compound (I) showing the atom labeling scheme of the asymmetric unit and 30% probability displacement ellipsoids. A crystallographic inversion center generates the complete molecule. Only the major component (S1A/C1A/C2A/C3A/C4A) of the disordered thiophene ring (occupancy: 0.719) is displayed.
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Fap1: Molecular structure of the title compound (I) showing the atom labeling scheme of the asymmetric unit and 30% probability displacement ellipsoids. A crystallographic inversion center generates the complete molecule. Only the major component (S1A/C1A/C2A/C3A/C4A) of the disordered thiophene ring (occupancy: 0.719) is displayed.


Di-μ-bromido-bis-{[N,N-dimethyl-N'-(thio-phen-2-yl-methyl-idene)ethane-1,2-diamine]-copper(I)]}.

Goh C, Remillard ZD, Martinez AP, Keeley AC, Jasinski JP - Acta Crystallogr Sect E Struct Rep Online (2012)

Molecular structure of the title compound (I) showing the atom labeling scheme of the asymmetric unit and 30% probability displacement ellipsoids. A crystallographic inversion center generates the complete molecule. Only the major component (S1A/C1A/C2A/C3A/C4A) of the disordered thiophene ring (occupancy: 0.719) is displayed.
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC3344410&req=5

Fap1: Molecular structure of the title compound (I) showing the atom labeling scheme of the asymmetric unit and 30% probability displacement ellipsoids. A crystallographic inversion center generates the complete molecule. Only the major component (S1A/C1A/C2A/C3A/C4A) of the disordered thiophene ring (occupancy: 0.719) is displayed.
Bottom Line: In the crystal structure of the title compound, [Cu(2)Br(2)(C(9)H(14)N(2)S)(2)], the mol-ecule resides about a crystallographic inversion center.The thio-phene ring is disordered over two sites, with occupancies of 0.719 (3) and 0.281 (3).Weak C-H⋯π inter-actions feature in the crystal packing.

View Article: PubMed Central - HTML - PubMed

ABSTRACT
In the crystal structure of the title compound, [Cu(2)Br(2)(C(9)H(14)N(2)S)(2)], the mol-ecule resides about a crystallographic inversion center. The coordination sphere around each copper ion has a distorted tetra-hedral geometry, with ligation by two bridging bromide ions, an amine N atom and an imine N atom. The thio-phene ring is disordered over two sites, with occupancies of 0.719 (3) and 0.281 (3). Weak C-H⋯π inter-actions feature in the crystal packing.

No MeSH data available.


Related in: MedlinePlus