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catena-Poly[[penta-μ-benzoato-μ-chlorido-dioxanedineodymium(III)] dioxane 2.5-solvate].

Bertke JA, Oliver AG, Henderson KW - Acta Crystallogr Sect E Struct Rep Online (2012)

Bottom Line: There is a small amount of void space which is filled with five disordered dioxane solvent mol-ecules per unit cell.Acta Cryst.D65, 148-155].

View Article: PubMed Central - HTML - PubMed

Affiliation: 251 Nieuwland Science Hall, Department of Chemistry and Biochemistry, University of Notre Dame, Notre Dame, IN 46556-5670, USA.

ABSTRACT
The asymmetric unit of the title compound, [Nd(2)(C(6)H(5)COO)(5)Cl(C(4)H(8)O(2))]·2.5C(4)H(8)O(2), consists of two Nd(III) ions bridged by one Cl(-) ion, five benzoate ions and one coordinating 1,4-dioxane mol-ecule. One Nd(III) ion is nine-coordinate, with a very distorted monocapped square-anti-prismatic geometry. It is coordinated by two chelating carboxyl-ate groups, three monodentate carboxyl-ate groups, one chloride ion and one dioxane mol-ecule. A second independent Nd(III) ion is eight-coordinated in a distorted square-anti-prismatic geometry by one chelating carboxyl-ate group, five monodentate carboxyl-ate groups and one chloride ion. The chains of the extended structure are parallel to the crystallographic b axis. There is a small amount of void space which is filled with five disordered dioxane solvent mol-ecules per unit cell. The intensity contribution of the disordered solvent molecules was removed by applying the SQUEEZE procedure in PLATON [Spek (2009). Acta Cryst. D65, 148-155].

No MeSH data available.


Related in: MedlinePlus

Extended structure, with the one-dimensional chain extending along the b-axis. All phenyl rings of the benzoate ligands and all hydrogen atoms have been removed for clarity.
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Fap2: Extended structure, with the one-dimensional chain extending along the b-axis. All phenyl rings of the benzoate ligands and all hydrogen atoms have been removed for clarity.


catena-Poly[[penta-μ-benzoato-μ-chlorido-dioxanedineodymium(III)] dioxane 2.5-solvate].

Bertke JA, Oliver AG, Henderson KW - Acta Crystallogr Sect E Struct Rep Online (2012)

Extended structure, with the one-dimensional chain extending along the b-axis. All phenyl rings of the benzoate ligands and all hydrogen atoms have been removed for clarity.
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC3344409&req=5

Fap2: Extended structure, with the one-dimensional chain extending along the b-axis. All phenyl rings of the benzoate ligands and all hydrogen atoms have been removed for clarity.
Bottom Line: There is a small amount of void space which is filled with five disordered dioxane solvent mol-ecules per unit cell.Acta Cryst.D65, 148-155].

View Article: PubMed Central - HTML - PubMed

Affiliation: 251 Nieuwland Science Hall, Department of Chemistry and Biochemistry, University of Notre Dame, Notre Dame, IN 46556-5670, USA.

ABSTRACT
The asymmetric unit of the title compound, [Nd(2)(C(6)H(5)COO)(5)Cl(C(4)H(8)O(2))]·2.5C(4)H(8)O(2), consists of two Nd(III) ions bridged by one Cl(-) ion, five benzoate ions and one coordinating 1,4-dioxane mol-ecule. One Nd(III) ion is nine-coordinate, with a very distorted monocapped square-anti-prismatic geometry. It is coordinated by two chelating carboxyl-ate groups, three monodentate carboxyl-ate groups, one chloride ion and one dioxane mol-ecule. A second independent Nd(III) ion is eight-coordinated in a distorted square-anti-prismatic geometry by one chelating carboxyl-ate group, five monodentate carboxyl-ate groups and one chloride ion. The chains of the extended structure are parallel to the crystallographic b axis. There is a small amount of void space which is filled with five disordered dioxane solvent mol-ecules per unit cell. The intensity contribution of the disordered solvent molecules was removed by applying the SQUEEZE procedure in PLATON [Spek (2009). Acta Cryst. D65, 148-155].

No MeSH data available.


Related in: MedlinePlus